Russian Chemical Bulletin p. 1848 - 1850 (1997)
Update date:2022-08-11
Topics:
Pavlov
Nazin
Thermal decomposition of dinitramide onium salts proceeds via the dissociative mechanism when pKa of the base is lower than 5.0 and via the monomolecular decay of the anion at pKa > 7.0. On going from the melt to the solid state, the reaction mechanism does not change, and the rate decreases by 1-2 orders of magnitude. No anomalous effects inherent in dinitramide metal salts in the solid phase are observed during decomposition of onium salts.
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