Monatshefte fur Chemie p. 1257 - 1263 (2004)
Update date:2022-08-11
Topics:
Mirkhani, Valiollah
Tangestaninejad, Shahram
Moghadam, Majid
Yadollahi, Bahram
Alipanah, Ladan
Efficient esterification of primary and sterically-hindered secondary or tertiary alcohols with acetic anhydride was achieved in the presence of ammonium decatungestocerate(IV) icosahydrate, (NH4)8[CeW 10O36]·OH2O, as catalyst in high yields. Primary and secondary alcohols were also converted to their corresponding acetates and formates with acetic acid and ethyl formate in the presence of this catalyst. Easy work-up, non-toxicity, reusability, and stability of the catalyst are noteworthy advantages of this method. Springer-Verlag 2004.
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