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ChemComm
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DOI: 10.1039/C6CC02169G
COMMUNICATION
Journal Name
This method also opens up the opportunity to perform 12 C. M. McGuirk, M. J. Katz, C. L. Stern, A. A. Sarjeant, J. T. Hupp,
versatile couplings of α,β-unsaturated alcohols with reactive O. K. Farha and C. A. Mirkin, J. Am. Chem. Soc., 2015, 137, 919.
methylene compounds to form extended conjugated systems. 13 (a) H. Fei and S. M. Cohen, J. Am. Chem. Soc., 2015, 137, 2191;
With the abundance of catalytic applications for metal NPs as
well as functionalised MOF materials, there is considerable
scope for further development of NP/MOF materials targeted
towards other cascade processes. These hybrid catalysts could
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have
a significant impact on catalytic transformations 14 (a) A. Abad, A. Corma and H. García, Chem. Eur. J., 2008, 14,
employed in the fine-chemical or pharmaceutical industries,
where multi-step reactions are commonplace.
C.S.H and W.R.W thank both the University of
Southampton for a Vice-Chancellor’s scholarship and A*STAR,
Singapore for ARAP scholarships in support of this work. Dr Jia
212; (b) H. Tsunoyama, H. Sakurai, Y. Negishi and T. Tsukuda, J.
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Cao, Acc. Chem. Res., 2013, 47, 793.
Min Chin is thanked for helpful discussions and RR is grateful 15 A. Dhakshinamoorthy and H. Garcia, Chem. Soc. Rev., 2012, 41,
to the EPSRC (UK) for funding (EP/K014714/1).
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