Bulletin of the Chemical Society of Japan p. 171 - 174 (1984)
Update date:2022-08-10
Topics:
Nakayama
Torigata
In this study, from the solid-liquid phase diagrams for 19 binary mixtures of tetrabutylammonium carboxylate-water, the effect of the shape and/or length of the alkyl group of a carboxylate anion on the stability (i. e. , melting point) and the crystal structure (i. e. , hydration number) of their clathrate hydrates has been systematically examined. These fundamental data would also offer a guiding principle, for example, for highly selective separation of a specific carboxylate anion from an aqueous solution containing several kinds of carboxylate anions by means of the formation of a mixed clathrate hydrate of tetrabutylammonium carboxylates.
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