Chemistry Letters p. 1339 - 1342 (1985)
Update date:2022-08-30
Topics:
Kaneda, Kiyotomi
Mori, Teruaki
Kobayashi, Masaya
Imanaka, Toshinobu
Teranishi, Shiichiro
Propionitrile is selectively formed by reduction of nitropropane using CO and H2O (8 atm of CO, 4O deg C).Rhodium carbonyls combined with bases show high catalytic activity.Amines with high pKa values as additives give high yields of propionitrile.
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