Journal of Physical Chemistry p. 3113 - 3117 (1985)
Update date:2022-08-17
Topics:
Shultz, M. J.
Tricca, Robert E.
Berets, S. L.
Kostas, Christopher
Yam, Loretta M.
The laser-induced isomerization of methyl isocyanide has previously been shown to exhibit a marked pressure dependence; large-scale isomerization occurs when threshold conditions have been exceeded.Recent investigations of this large-scale isomerization have shown that the threshold is not due to a thermal mechanism as previously believed.In this work, the characteristics of the threshold are examined and it is shown that the threshold is a result of a radical channel.
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