Paper
RSC Advances
within immediate to 7 min. In addition, the catalytic efficiency 12 L. Wu, A. Mendoza-Garcia, Q. Li and S. Sun, Chem. Rev.,
of introduced nanocatalysts were tested toward NaBH4 reduc- 2016, 116, 10473.
tion of different nitro compounds. All reduction reactions were 13 H. Pardoe, W. Chua-anusorn, T. G. S. Pierre and J. Dobson, J.
performed in H2O within 3–15 min to obtain amines in high Magn. Magn. Mater., 2001, 225, 41.
yields. CoFe2O4@AA-M (Co, V) were easily separated from the 14 B. Zumreoglu-Karan, Coord. Chem. Rev., 2006, 250, 2295.
reaction combination using an external magnet and reused in 15 Sh. Zhao, L. Huang and Y. F. Song, Eur. J. Inorg. Chem., 2013,
both oximation and reduction reactions several times without
considerable loss of its catalytic activity. Finally, these catalysts 16 R. Raja, G. Sankar and J. M. Thomas, J. Am. Chem. Soc., 2001,
are preferable over the other catalysts because of their supreme 123, 8153.
properties, such as easy preparation, short reaction times, clean 17 S. Zhao, L. Liu and Y. F. Song, Dalton Trans., 2012, 41, 9855.
1659.
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reaction conditions, suppression of any side product and 18 R. Garcıa-Alvarez, A. E. Dıaz-Alvarez, J. Borge, P. Crochet and
simple work-up method. So, we believe that nano CoFe2O4@AA- V. Cadierno, Organometallics, 2012, 31, 6482.
Co and CoFe2O4@AA-V systems could be considered as useful 19 D. Tyagi, R. K. Rai, A. D. Dwivedi, S. M. Mobina and
and new addition to the present methodologies in these scopes.
S. K. Singh, Inorg. Chem. Front., 2015, 2, 116.
20 P. Han, J. Li, C. Li Xing, M. Zhao, Q. Xia Han and M. Xue Li,
Inorg. Chem. Commun., 2019, 110, 107592.
21 S. Z. Xing, Q. X. Han, Z. L. Shi, S. G. Wang, P. P. Yang, Q. Wu
and M. X. Li, Dalton Trans., 2017, 46, 11537.
Conflicts of interest
There are no conicts to declare.
22 G. Sosnovsky, J. A. Krogh and S. G. Umhoefer, Synthesis,
1979, 9, 722.
23 P. Miller and D. H. Kaufman, Synlett, 2000, 8, 1169.
Acknowledgements
We gratefully acknowledge the support of this work by Univer- 24 R. S. Ramon, J. Bosson, S. Diez-Gonzalez, N. Marion and
sity of Kurdistan.
S. P. Nolan, J. Org. Chem., 2010, 75, 1197.
25 E. Abele, R. Abele, O. Dzenitis and E. Lukevics, Chem.
Heterocycl. Compd., 2003, 39, 3.
26 I. Damljanovic, M. Vukicevic and R. D. Vukicevic, Monatsh.
Chem., 2006, 137, 301.
References
1 P. T. Anastas and J. C. Warner, Green Chemistry: Theory and
Practice, Oxford university, Oxford, 1998, vol. 1.
2 (a) R. J. White, R. Luque, V. L. Budarin, J. H. Clark and
27 I. M. Osadchenko and A. P. Tomilov, Russ. J. Appl. Chem.,
2002, 75, 511.
D. J. Macquarrie, Chem. Soc. Rev., 2009, 38, 481; (b) 28 U. P. Lad, M. A. Kulkarni and R. S. Patil, Rasayan J. Chem.,
A. Schatz, T. R. Long, R. N. Grass, W. J. Stark, P. R. Hanson
and O. Reiser, Adv. Funct. Mater., 2010, 20, 4323.
3 (a) M. B. Gawande, A. K. Rathi, P. S. Branco, T. M. Potewar,
2010, 3, 425.
29 D. Setamdideh, B. Khezri and S. Esmaeilzadeh, J. Chin.
Chem. Soc., 2012, 59, 1119.
A. Velhinho, I. D. Nogueira, A. Tolstogouzov, C. Amjad, 30 J. J. Xia and G. W. Wang, Molecules, 2007, 12, 231.
A. Ghumman and O. M. N. D. Teodoro, RSC Adv., 2013, 3, 31 J. J. Guo, T.-S. Jin, S.-L. Zhang and T. S. Li, Green Chem., 2001,
3611; (b) M. B. Gawande, S. N. Shelke, A. Rathi,
3, 193.
P. S. Branco and R. K. Pandey, Appl. Organomet. Chem., 32 H. Sharghi and M. Hosseini, Synthesis, 2002, 8, 1057.
´
2012, 26, 395; (c) M. B. Gawande, V. D. B. Bonifacio, 33 B. Zeynizadeh and M. Karimkoshteh, J. Nanostruct. Chem.,
R. S. Varma, I. D. Nogueira, N. Bundaleski, C. Amjad, 2013, 3, 57.
A. Ghumman, O. M. N. D. Teodoro and P. S. Branco, Green 34 M. Karimkoshteh, M. Bagheri and B. Zeynizadeh, Nanochem.
Chem., 2013, 15, 1226. Res., 2016, 1, 57.
4 R. Sato Turtelli, G. V. Duong, W. Nunes, R. Grossinger and 35 P. N. Ghozlojeh and D. Setamdideh, Orient. J. Chem., 2015,
M. Knobel, J. Magn. Magn. Mater., 2008, 320, 339.
31, 1823.
5 E. S. Murdock, R. F. Simmons and R. Davidson, IEEE Trans. 36 G. L. Kad, M. Bhandari, J. Kaur, R. Rathee and J. Singh, Green
Magn., 1992, 28, 3078. Chem., 2001, 3, 275.
6 P. Majewski and B. Thierry, Crit. Rev. Solid State Mater. Sci., 37 B. Zeynizadeh and E. Amjadi, Asian J. Chem., 2009, 21, 3611.
2007, 32, 203.
38 B. R. Kim, G. H. Sung, J. J. Kim and Y. J. Yoon, J. Korean
Chem. Soc., 2013, 57, 295.
7 A. K. Gupta and M. Gupta, Biomaterials, 2005, 26, 3995.
¨
8 S. Shylesh, V. Schunemann and W. R. Thiel, Angew. Chem., 39 J. T. Li, X. L. Li and T. S. Li, Ultrason. Sonochem., 2006, 13,
Int. Ed., 2010, 49, 3428.
200.
9 V. Polshettiwar and R. S. Varma, Green Chem., 2010, 12, 743. 40 L. Saikia, J. M. Baruah and A. J. Thakur, Org. Med. Chem.
10 D. L. Graham, H. A. Ferreira and P. P. Freitas, Trends
Biotechnol., 2004, 22, 455.
11 C. Pereira, A. M. Pereira, C. Fernandes, M. Rocha, R. Mendes,
Lett., 2011, 1, 1.
41 K. Ramanjaneyulu, P. Seshagiri Rao, T. Rambabu, K. Jayarao,
C. B. T. Sundari Devi and B. Venkateswara Rao, Der Pharma
Chem., 2012, 4, 473.
´
´
M. P. Fernandez-Garcıa, A. Guedes, P. B. Tavares,
`
´
J. M. Greneche and J. o. P. Araujo, Chem. Mater., 2012, 24, 42 H. Sharghi and M. H. Sarvari, J. Chem. Res., 2000, 1, 24.
1496.
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