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tungstic acid has a more favorable ecotoxicological profile
than phosphotungstic acid. A convenient method for puri-
fication of the product has also been highlighted. Future
developments will focus on further optimization of the iso-
lation procedures and recovery of the catalytic ingredients.
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(2000) Oxidative cleavage of the double bond of monoenic fatty
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eneimine/polyoxometalate synzymes as catalysts for the oxida-
tion of hydrophobic substrates in water with hydrogen peroxide.
J Am Chem Soc 126:11762–11763
Acknowledgments The authors warmly thank Prof. Thierry
Ollevier (Université Laval, Canada) for helpful discussions. The
authors thank MIUR (Progetto Rebiochem—Cluster 2012) for finan-
cial support. The authors also thank Solvay (Rosignano, Italy) for a
generous loan of hydrogen peroxide (60 % v/v).
13. Santacesaria E, Ambrosio M, Sorrentino A, Tesser R, Di Serio
M (2003) Double bond oxidative cleavage of monoenic fatty
chains. Catal Today 79–80:59–65
14. Oakley MA, Woodward S, Coupland K, Parker D, Temple-Heald
C (1999) Practical dihydroxylation and C–C cleavage of unsatu-
rated fatty acids. J Mol Catal A Chem 150:105–111
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