Journal of Organometallic Chemistry p. 119 - 124 (1994)
Update date:2022-08-11
Topics:
Boisselier, Veronique Le
Dunach, Elisabet
Postel, Michele
Bismuth(III)mandelate catalyzes the oxidative C-C bond cleavage of a series of styrene epoxides in DMSO, to the corresponding aryl carboxylic acids.The reaction is accelerated in the presence of electron-donating groups substituting the phenyl ring.A good Hammet correlation of log kobs versus ? has been obtained, with a ρ of -1.08.Key words: Bismuth; Aryl epeoxide cleavage; Oxidation; Substituent effects; Bi(III) catalysis; Hammet correlation
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