Journal of Organometallic Chemistry p. 282 - 287 (2015)
Update date:2022-08-15
Topics:
Iranpoor, Nasser
Firouzabadi, Habib
Etemadi-Davan, Elham
Abstract The convenient nickel-catalyzed carbonylative coupling of aryl iodides with Ph3SnCl or Ph3SnOEt for synthesis of unsymmetrical diaryl ketones under phosphine-free condition is reported. The reaction occurs efficiently in the presence of Cr(CO)6 as an easy handling solid source of carbon monoxide at atmospheric pressure and 100 °C in DMF under air to deliver the desired ketones in high yield.
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