RSC Advances p. 17105 - 17109 (2014)
Update date:2022-08-17
Topics:
Qi, Shi-Chao
Zhang, Lu
Wei, Xian-Yong
Hayashi, Jun-Ichiro
Zong, Zhi-Min
Guo, Lu-Lu
We have developed a Ni/ZSM-5 catalyst and utilised it to completely hydrogenate a series of condensed arenes, including naphthalene, anthracene and phenanthrene, under relatively mild conditions. The yields of decalin, perhydroanthracene and perhydrophenanthrene reached 100%, 98.8% and 25.8%, respectively. By analyzing the isomer distribution of the perhydroarenes, we proposed a mechanism of biatomic hydrogen transfer, which was further proven via the hydrogenation of 9,10-diphenylanthracene. Through hydrotreatment over the Ni/ZSM-5 catalyst, both high-temperature coal tar rich in condensed arenes and low-temperature coal tar mixing arenes with alkanes were greatly upgraded. The majority of arenes in the coal tars were deeply and even completely hydrogenated, which may open up a route for further processing and application of coal tar as clean fuels.
View MoreShanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
TIANJIN NORTH JINHENG CHEMICAL PLANT.
Contact:0086-22-59952083
Address:DongShigu Country In JiXian TianJin China
Chengdu Daoerji Medical Technology Co., Ltd
Contact:86-28-85528891
Address:Southwest University For Nationalities,Wuhou District,Chengdu City,Sichuan Province
Jiangsu Cale New Material Co.ltd
Contact:+86-515-88334667/88203550
Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD
Contact:+86-755-82412922
Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Doi:10.1039/c5ra02349a
(2015)Doi:10.1007/s11164-019-03802-7
(2019)Doi:10.1002/open.202000236
(2020)Doi:10.1039/d0ob01200a
(2020)Doi:10.1046/j.1444-2906.2000.00002.x
(1931)Doi:10.1021/acs.organomet.0c00429
(2020)