Journal of Molecular Structure p. 499 - 504 (1989)
Update date:2022-08-17
Topics:
Ilczyszyn, Marek
Ratajczak, Henryk
Ladd, John A.
Low temperature 1H NMR studies of the bridging OHN signal in the hydrogen-bonded complex formed between 2,3,5,6-tetrachlorophenol and N,N-dimethylaniline in C2H5Cl solution have shown that separate signals for the molecular and ion-pair forms of the complex can be observed below -135 deg C (138 K).Analyses of the observed lineshapes have yielded values for the thermodynamic quantities ΔH0, ΔS0 as well as for the activation quantities ΔH<*>, ΔS<*>.
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