Tetrahedron p. 9755 - 9758 (1996)
Update date:2022-08-25
Topics:
Pasenok, Sergej V.
De Roos, Marijn E.
Appel, Wolfgang K.
Ammonium- and phosphoniumperfluorocyclobutane glides 1 and 2, prepared from perfluorocyclobutene and tertiary amines or phosphines can be used as a masked fluoride anion source. These properties have been demonstrated in several reactions. Ylides 1 and 2 cleave C-Si or O-Si bonds, cause dimerisation of fluoroolefins or react with acid chlorides or activated aromatic compounds under halogen exchange.
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