Tetrahedron p. 3787 - 3790 (2018)
Update date:2022-08-11
Topics:
Kim, Dalton
Nash, Aaron
De Brabander, Jef
Tambar, Uttam K.
A concise and convergent total synthesis of sparstolonin B was developed. A palladium-catalyzed aldehyde α-arylation was utilized to construct the carbon skeleton of the natural product. A subsequent simple one-pot procedure effected global deprotection and closure of the final two rings via an unusual autoredox mechanism for the conversion of a bis-hydroquinone intermediate to the natural product. The 6 step synthetic sequence was realized in 18% overall yield.
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