Inorganic Chemistry
Article
with a rich interplay of As3+/As5+ chemistry, the details of
which is dictated by the nature of M and the basicity of the flux.
(11) Wu, Y. D.; Bensch, W. J. Alloys Compd. 2011, 509, 4452.
(12) Wu, Y. D.; Bensch, W. J. Alloys Compd. 2012, 511, 35.
(13) Feher, F. Handbuch der Praparativen Anorganischen Chemie;
̈
Brauer, G., Ed.; Ferdinand Enke: Stuttgart, Germany, 1954; Vol. 1, pp
280−281.
ASSOCIATED CONTENT
* Supporting Information
■
S
(14) Kraus, W.; Nolze, G. PowderCell 2.3; Federal Institute for
Materials Research and Testing (BAM) : Berlin, Germany, 1998.
(15) (a) Pankove, J. I. In Optical Processes in Semiconductors; Dover
Publications: New York, 1975. (b) Kanatzidis, M. G.; McCarthy, T. J.;
Tanzer, T. A.; Chen, L. H.; Iordanidis, L.; Hogan, T.; Kannewurf, C.
R.; Uher, C.; Chen, B. X. Chem. Mater. 1996, 8, 1465. (c) Liao, J. H.;
Kanatzidis, M. G. Chem. Mater. 1993, 5, 1561. (d) Trikalitis, P. N.;
Rangan, K. K.; Bakas, T.; Kanatzidis, M. G. J. Am. Chem. Soc. 2002,
124, 12255.
The powder X-ray patterns, experimental details, and X-ray
crystallographic files (CIF) for NaEuAsS4 and Na2EuAs2S5.
This material is available free of charge via the Internet at
AUTHOR INFORMATION
Corresponding Author
■
(16) X-Area, Version 1.39; STOE & Cie GmbH: Darmstadt,
Germany, 2006.
(17) SHELXTL, Version 5.03; Siemens Analytical X-ray Instruments:
Madison, WI, 1995.
Notes
The authors declare no competing financial interest.
(18) Eick, H. A. J. Am. Chem. Soc. 1958, 80, 43. Bakhtiyarov, I. B.;
Rustamov, P. G.; Nakhmetov, S. M.; Gasymov, V. A. Z. Anorg. Allg.
Chem. 1986, 533, 186.
(19) Aitken, J. A.; Chondroudis, K.; Young, V. G.; Kanatzidis, M. G.
Inorg. Chem. 2000, 39, 1525.
(20) (a) Wu, Y.; Naether, C.; Bensch, W. Inorg. Chem. 2006, 45,
8835. (b) Korzenski, M. B.; Schimek, G. L.; Kolis, J. W. Solid State Sci.
2000, 2, 377. (c) Iyer, R. G.; Kanatzidis, M. G. Inorg. Chem. 2004, 43,
3656.
ACKNOWLEDGMENTS
■
Financial support from the National Science Foundation (Grant
DMR-1104965) is gratefully acknowledged. This work made use
of the SEM facilities at the Electron Probe Instrumentation
Center (EPIC), Northwestern University. FT-Raman spectro-
scopic study was done at the Analytical Service Laboratory (ASL),
Northwestern University.
(21) Chondroudis, K.; McCarthy, T. J.; Kanatzidis, M. G. Inorg.
Chem. 1996, 35, 840.
REFERENCES
■
(1) (a) Zakery, A.; Elliott, S. R. J. Non-Cryst. Solids 2003, 330, 1.
(b) Liang, Z. J. Non-Cryst. Solids 1991, 127, 298.
(22) (a) Kanatzidis, M. G. Phosphorus, Sulfur Silicon Relat. Elem.
1994, 93, 159. (b) Sayettat, J.; Bull, L. M.; Gabriel, J. C. P.; Jobic, S.;
Camerel, F.; Marie, A. M.; Fourmigue, M.; Batail, P.; Brec, R.;
Inglebert, R. L. Angew. Chem., Int. Ed. 1998, 37, 1711. (c) Kim, K. W.;
Kanatzidis, M. G. J. Am. Chem. Soc. 1998, 120, 8124.
(23) Aitken, J. A.; Larson, P.; Mahanti, S. D.; Kanatzidis, M. G. Chem.
Mater. 2001, 13, 4714.
(2) (a) Ye, N.; Chen, Q.; Wu, B.; Chen, C. J. Appl. Phys. 1998, 84,
555. (b) Distanov, V. E. N.; B., G.; Kirdyashkin, A. G.; Serboulenko,
M. G. J. Cryst. Growth 2002, 235, 457. (c) Feichtner, J. D.; Roland, G.
W. Appl. Opt. 1972, 11, 993. (d) Bera, T. K.; Song, J. H.; Freeman, A.
J.; Jang, J. I.; Ketterson, J. B.; Kanatzidis, M. G. Angew. Chem., Int. Ed.
2008, 47, 7828. (e) Bera, T. K.; Jang, J. I.; Ketterson, J. B.; Kanatzidis,
M. G. J. Am. Chem. Soc. 2009, 131, 75. (f) Song, J. H.; Freeman, A. J.;
Bera, T. K.; Chung, I.; Kanatzidis, M. G. Phys. Rev. B 2009, 79, 245203.
(g) Bera, T. K.; Song, J. H.; Freeman, A. J.; Jang, J. I.; Ketterson, J. B.;
Kanatzidis, M. G. J. Am. Chem. Soc. 2010, 132, 3484.
(3) (a) Iyer, R. G.; Do, J.; Kanatzidis, M. G. Inorg. Chem. 2003, 42,
1475. (b) Iyer, R. G.; Kanatzidis, M. G. Inorg. Chem. 2002, 41, 3605.
(c) Iyer, R. G.; Bilc, D.; Mahanti, S. D.; Kanatzidis, M. G. Solid-State
Chem. Inorg. Mater. 2005, 848, 83. (d) Do, J.; Kanatzidis, M. G.
J. Alloys Compd. 2004, 381, 41.
(24) Gostojic, M.; Edenharter, A.; Nowacki, W.; Engel, P. Z.
Kristallogr. 1982, 158, 43.
(25) Takeu
127, 349.
́
chi, Y.; Ohmasa, M.; Nowacki, W. Z. Kristallogr. 1968,
(26) Chou, J.-H.; Hanko, J. A.; Kanatzidis, M. G. Inorg. Chem. 1997,
36, 4.
(27) (a) Pan, Y.; Jin, Q.; Chen, J.; Zhang, Y.; Jia, D. Inorg. Chem.
2009, 48, 5412. (b) Jia, D. X.; Zhao, Q. X.; Dai, J.; Zhang, Y.; Zhu, Q.
Y., Z. Anorg. Allg. Chem. 2006, 632, 349. (c) Jia, D. X.; Zhao, Q. X.;
Song, L. F.; Zhang, Y.; Dai, C. Chin. J. Struct. Chem. 2006, 25, 1110.
(d) Kromm, A.; Sheldrick, W. S. Z. Anorg. Allg. Chem. 2008, 634, 121.
(e) Kanatzidis, M. G.; Chou, J.-H. J. Solid State Chem. 1996, 127, 186.
(28) Bakhtiyarov, I. B.; Rustamov, P. G.; Nakhmetov, S. M.;
Gasymov, V. A. Z. Anorg. Allg. Chem. 1986, 533, 186.
(4) (a) Kanatzidis, M. G.; Sutorik, A. C. Prog. Inorg. Chem. 1995, 43,
151. (b) Sunshine, S. A.; Kang, D.; Ibers, J. A. J. Am. Chem. Soc. 1987,
109, 6202. (c) Kanatzidis, M. G.; Park, Y. Chem. Mater. 1990, 2, 99.
(5) Sheldrick, W. S.; Wachhold, M. Angew. Chem., Int. Ed. Engl. 1997,
36, 206.
(6) (a) Pan, Y.; Jin, Q.; Chen, J.; Zhang, Y.; Jia, D. Inorg. Chem. 2009,
48, 5412. (b) Wang, X.; Sheng, T.-L.; Hu, S.-M.; Fu, R.-B.; Chen, J.-S.;
Wu, X.-T. J. Solid State Chem. 2009, 182, 913. (c) Wachhold, M.;
Kanatzidis, M. G. Inorg. Chem. 2000, 39, 2337. (d) Wachhold, M.;
Kanatzidis, M. G. Inorg. Chem. 1999, 38, 3863. (e) Wachhold, M.;
Kanatzidis, M. G. Z. Anorg. Allg. Chem. 2000, 626, 1901. (f) Chou, J.-
H.; Kanatzidis, M. G. Inorg. Chem. 1994, 33, 1001. (g) Fu, M.-L.; Guo,
G.-C.; Liu, X.; Chen, W.-T.; Liu, B.; Huang, J.-S. Inorg. Chem. 2006,
45, 5793. (h) Dehnen, S.; Melullis, M. Coord. Chem. Rev. 2007, 251,
1259. (i) Chou, J. H.; Hanko, J. A.; Kanatzidis, M. G. Inorg. Chem.
1997, 35, 4.
(7) Bera, T. K.; Kanatzidis, M. G. Inorg. Chem. 2008, 47, 7068.
(8) (a) Evenson, C. R.; Dorhout, P. K. Inorg. Chem. 2001, 40, 2875.
(b) Evenson, C. R.; Dorhout, P. K. Inorg. Chem. 2001, 40, 2884.
(c) Aitken, J. A.; Chondroudis, K.; Young, V. G. Jr.; Kanatzidis, M. G.
Inorg. Chem. 2000, 39, 1525. (d) Kanatzidis, M. G. Curr. Opin. Solid
State Mater. Sci. 1997, 2, 139.
(9) Kang, D.; Schleid, T. Z. Anorg. Allg. Chem. 2009, 635, 2170.
(10) Wu, Y. D.; Bensch, W. Inorg. Chem. 2009, 48, 2729.
4299
dx.doi.org/10.1021/ic202781c | Inorg. Chem. 2012, 51, 4293−4299