MALENKOVSKAYA et al.
1198
C6H4], 3.92–4.12 m (14Н, С2Н, С4Н), 4.20 m (28Н,
С6Н2), 4.22 m (14Н, С5Н), 4.26 m (14Н, С3Н), 5.46
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3
br.s (7Н, С1Н), 7.54 d (2Н, С6Н4, J 7.9 Hz), 7.66 d
3
(2Н, С6Н4, J 9.9 Hz). 13С NMR spectrum, δ, ppm, in
2. Kurochkina, G.I., Grachev, M.K., and Batalova, T.A.,
D2O: 16.8 [HC(CH3)2], 21.8 [HC(CH3)C6H4], 25.2
(NCH2CH2CH2), 25.4 (NCH2CH2), 30.0 (С6Н4СН2
СН), 44.4 [HC(CH3)2], 48.0, 48.2 (NCH2), 57.4 (С6’),
59.7 (С6), 67.2 (С5’),**** 71.9 [(O)CCH(CH3)C6H4], 72.1
(С5), 72.3 (С2), 73.3 (С3), 81.0 (С4), 102.1 (С1), 126.6,
129.1 (C6H4), 139.4, 140.8 (C6H4-ipso), 183.0 [C(O)].
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Coll., 2004, vol. 10, p. 690.
1
Inclusion compound B. Н NMR spectrum, δ,
ppm, in D2O: 1.25–1.45 m (2Н, NCH2CH2CH2), 1.34 d
3
[12H, HC(CH3)2, J 7.0 Hz], 1.79–1.89 m (4Н, NCH2·
CH2СН2СН2СН2СН2N), 1.80 d [6H, HC(CH3)C6H4, 3J
6.4 Hz], 2.05–2.15 m (2H, NCH2CH2), 2.22–2.35 m
3
[2H, HC(CH3)2], 2.95 d (4Н, С6Н4СН2СН, J 7.0 Hz),
3.42–3.45 m (4Н, NСН2), 3.80–3.95 m [2H, (O)CCH·
(CH3)C6H4], 3.95–4.15 m (28Н, С2Н, С4Н), 4.24 m
(14Н, С5Н), 4.25 m (28Н, С6Н2), 4.26 m (14Н, С3Н),
7. Grachev, M.K., Edunov, A.V., Kurochkina, G.I.,
Soboleva, N.O., Vasyanina, L.K., and Nifant’ev, E.E.,
Russ. Chem. Bull., 2012, vol. 61, p. 181.
3
5.47 br.s (14Н, С1Н), 7.54 d (4Н, С6Н4, J 7.9 Hz),
8. Wood, D.J., Hruska, F.E., and Saenger, W., J. Am.
Chem. Soc., 1977, vol. 99, p. 1735; Smith, C.Z.,
and Utley, J.H.P., Chem. Commun., 1981, p. 492;
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3
7.67 d (4Н, С6Н4, J 9.9 Hz). 13С NMR spectrum, δ,
ppm, in D2O: 18.8 [HC(CH3)2], 21.7 [HC(CH3)C6H4],
25.3 (NCH2CH2CH2), 26.0 (NCH2CH2), 29.9 (С6Н4·
СН2СН), 39.3 (NCH2CH2), 44.4 [HC(CH3)2], 48.2
(NCH2), 59.7 (С6’), 60.4 (С6), 67.0 (С5’), 71.7
[(O)CCH(CH3)C6H4], 72.0 (С5), 72.1 (С2), 73.3 (С3),
81.0 (С4), 83.5 (С4’), 102.0 (С1), 126.6, 129.1 (C6H4),
139.5, 140.9 (C6H4-ipso), 183.3 [C(O)].
The study was carried out as the State contract with
Ministry of Education and Science of the Russian
Federation and under the financial support of the Russian
Foundation for Basic Research (grant no. 12-03-00147).
10. Lecourt, T., Mallet, J.-M., and Sinaÿ, P., Tetrahedron
Lett., 2002, vol. 43, p. 5533; Song, L.X., Chin. Chem.
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**** In some cases, the signals of the nuclei of atoms C5' and even
C4', that are in the same carbohydrate moiety which contains a
substituent at C6' also significantly shifted in compare with the
signals C4 and C5 [4, 12].
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY Vol. 50 No. 8 2014