Journal of Physical Chemistry p. 4071 - 4073 (1981)
Update date:2022-08-24
Topics:
Toby, Sidney
Toby, Frina S.
The gas-phase reactions of ozone with cis-1,2-difluoroethene, trans-1,2-difluoroethene, trifluoroethene, and chlorotrifluoroethene are all accompanied by light with a maximum intensity at approximately 425 nm.A partial vibrational analysis of this emission is presented and it is concluded that the emitting species is the FCO radical, as previously suggested.A comparison is made between the enthalpy changes of the primary reactions between ozone and the fluoroethenes and their correlation with the identity of the emitting species.The exothermicity of the reaction correlates with the chemiluminescent reaction channel.
View MoreChongqing Shuangfeng Chemical Co.,Ltd
Contact:+86-23-49850156
Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Daicel Chiral Technologies (China)CO.,LTD
Contact:021-5046-0086*8
Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
website:http://www.win-winchemical.com
Contact:0086-577-64498589
Address:6F,No.396 Xingping Road,Longwan Industrial Zone
Laohekou huacheng Trade Co., Ltd.
Contact:+86-710-8360685
Address:No. 85, Beijing Road, Laohekou City, Hubei Province, China
Doi:10.1021/jo7013998
(2007)Doi:10.1016/j.jssc.2008.12.029
(2009)Doi:10.1021/acs.orglett.8b03035
(2018)Doi:10.1080/00397911.2021.1874016
(2021)Doi:10.1039/c3nj00508a
(2013)Doi:10.1016/j.jfluchem.2008.01.018
(2008)