fluoromethane

Base Information

• Chemical Name: fluoromethane
• CAS No.: 13453-52-6
• Molecular Formula: CH3F
• Molecular Weight: 32.0173
• Mol file: 13453-52-6.mol

Synonyms:

Chemical Property of fluoromethane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 0.673g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of fluoromethane

There total 6 articles about fluoromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-fluoroethylene (75-02-5,24981-14-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + formyl fluoride (1493-02-3) + monofluorocarbene (13453-52-6) + fluoroformyl radical (1871-24-5)

Guidance literature:

With ozone; under 50 Torr; Thermodynamic data; weak chemiluminescence at 440 nm; ΔH⁰ data for different reaction pathways (calculated from the formation enthalpies);

DOI:10.1021/j150626a024

Reference yield:

methylene (2465-56-7) → monofluorocarbene (13453-52-6)

Guidance literature:

With hydrogen fluoride; In gas; at 21.9 ℃; Kinetics; Mechanism; other temperatures, various partial pressures of HF;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) → difluoro-methylene (2154-59-8) + Carbonyl fluoride (353-50-4) + formyl fluoride (1493-02-3) + monofluorocarbene (13453-52-6) + fluoroformyl radical (1871-24-5)

Guidance literature:

With ozone; under 50 Torr; Thermodynamic data; chemiluminescence (CF2^* as identified emitters); ΔH⁰ (calculated from the formation enthalpies);

DOI:10.1021/j150626a024

upstream raw materials:

methylene

1-fluoroethylene

polytetrafluoroethylene

1,1,2-trifluoroethylene

Downstream raw materials:

methyl radical

Methyl fluoride

fluoromethyl

carbon nitride

Refernces

• 1、 Sadilek, Martin,Turecek, Frantisek. "Dissociations of Gas-Phase CHClF and CHCl2 Radicals and Cations following Collisional Electron Transfer. A Variable-Time Neutralization-Reionization and ab Initio Study". . p. 224 - 232. Retrieved 1996.
• 2、 Wagener, R.,Wagner, H. Gg.. "On the Reaction of CH2(a1A1) with HF". . p. 1096 - 1100. Retrieved 2007/10/02.