fluorocarbonyl

Base Information

• Chemical Name: fluorocarbonyl
• CAS No.: 1871-24-5
• Molecular Formula: CFO
• Molecular Weight: 47.0088
• Mol file: 1871-24-5.mol

Synonyms:

Chemical Property of fluorocarbonyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of fluorocarbonyl

There total 13 articles about fluorocarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-fluoroethylene (75-02-5,24981-14-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + formyl fluoride (1493-02-3) + monofluorocarbene (13453-52-6) + fluoroformyl radical (1871-24-5)

Guidance literature:

With ozone; under 50 Torr; Thermodynamic data; weak chemiluminescence at 440 nm; ΔH⁰ data for different reaction pathways (calculated from the formation enthalpies);

DOI:10.1021/j150626a024

Reference yield:

formyl fluoride (1493-02-3) + fluorine → fluoroformyl radical (1871-24-5) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

In gaseous matrix; react. of F atoms, generated from SF6 by IR irradn., in He or Ar with HFCO in the temp. range 298-368 K; monitored by HF detection by IR chemiluminescence technique; Kinetics;

DOI:10.1063/1.459601

Reference yield:

Chlorotrifluoroethylene (79-38-9,9036-80-0) → difluoro-methylene (2154-59-8) + Carbonyl fluoride (353-50-4) + fluoroformyl chloride (353-49-1) + chlorofluorocarbon (1691-88-9) + fluoroformyl radical (1871-24-5)

Guidance literature:

With ozone; under 50 Torr; Thermodynamic data; intense chemiluminescence at 425 nm (FCO^* as identified emitter); ΔH⁰ data for different reaction pathways (calculated from the formation enthalpies);

DOI:10.1021/j150626a024

upstream raw materials:

1-fluoroethylene

polytetrafluoroethylene

Chlorotrifluoroethylene

1,1,2-trifluoroethylene

Downstream raw materials:

Carbonyl fluoride

Refernces

• 1、 Adrian et al.. "". . p. 462. Retrieved 1965.
• 2、 Buckley, T. J.,Johnson, R. D.,Huie, R. E.,Zhang, Z.,Kuo, S.C.,Klemm, R. B.. "Ionization Energies, Appearance Energies, and Thermochemistry of CF2O and FCO". . p. 4879 - 4885. Retrieved 2007/10/02.
• 3、 Francisco, J. S.,Zhao, Y.. "The reaction of atomic fluorine with formyl fluoride: An experimental and theoretical study". . p. 276 - 286. Retrieved 2007/10/02.