REACTION OF PLATINUM COMPLEXES WITH (+)- -PINENE
1293
phenone, (+)- -pinene, (+)-limonene, K2PtCl4, and
RhCl3 4H2O were used.
4. da Silva Rocha, K.A., Kozhevnikov, I.V., and Gusev-
skaya, E.V., Appl. Catal., A, 2005, vol. 294, no. 1,
p. 106.
The
complexes
cis-[Pt(Me2SO)2Cl2],
cis-
[Pt(MeCN)2Cl2], [Rh(CO)2Cl]2 [24], (Et3NH)2[PtCl4],
(Et3NH)2[PtCl6] [25], [(Me2SO)2H]2[PtCl6] [26], and
[Pt(MeCOD)Cl2] [27] were synthesized by known
methods.
5. da Silva, M.J. and Gusevskaya, E.V., J. Mol. Catal.
A: Chem., 2001, vol. 176, nos. 1 2, p. 23.
6. Lajunen, M.K., J. Mol. Catal. A: Chem., 2001,
vol. 169, nos. 1 2, p. 33.
Dichloro[ 4-p-mentha-1,8(9)-diene]platinum(II).
Potassium tetrachloroplatinate(II), 35.9 mg, and (+)- -
pinene, 0.1 ml, were dissolved in 50 ml of 0.001 N
hydrochloric acid at room temperature. After
6 months (the solution was allowed to slowly evapo-
rate), 12.7 mg of the brown complex was filtered off.
Yield 36.5%. The X-ray diffraction data (bond lengths
and angles and coordinates of non-hydrogen atoms)
7. Gonsalves, J.A., Howarth, O.W., and Gusev-
skaya, E.V., J. Mol. Catal. A: Chem., 2002, vol. 185,
nos. 1 2, p. 97.
8. Robles-Dutenhefner, P.A., da Silva, M.J., Sales, L.S.,
Sousa, E.M.B., and Gusevskaya, E.V., J. Mol. Catal.
A: Chem., 2004, vol. 217, nos. 1 2, p. 139.
9. Spevak, V.N., Cand. Sci. (Chem.) Dissertation,
1
are given in Tables 1 and 2. IR spectrum, cm : 2962
Leningrad, 1971.
(
(
C H); 2278, 2257, 2249, 2123; 1643 ( C=C); 1518
C H, ring); 1450 ( C H, ring, CH3); 1157, 1132,
10. Price, J.H., Birk, J.P., and Wayland, B.B., Inorg.
Chem., 1978, vol. 17, no. 8, p. 2245.
1020, 1008 ( C H); 841, 823 (
774 ( C C, ring); 636.
and C H); 789,
C C
11. Suga, T., Hirata, T., and Aoki, T., Bull. Chem. Soc.
Jpn., 1982, vol. 55, no. 3, p. 914.
cis-Terpine hydrate was isolated from the same
reaction solution. Yield 54.0%. The bond lengths and
bond angles determined by X-ray analysis coincided
with those reported in [11]. 1H NMR spectrum
[(CD3)2SO], , ppm: 1.00 s (6H, CH3), 1.05 s (3H,
CH3), 1.21 m (4H, CH2), 1.50 t (4H, CH2, J = 14 Hz).
12. Kukushkin, Yu.N., Reaktsionnaya sposobnost’ ko-
ordinatsionnykh soedinenii (Reactivity of Coordina-
tion Compounds), Leningrad: Khimiya, 1987
13. Metody elementoorganicheskoi khimii. Tipy metal-
loorganicheskikh soedinenii perekhodnykh metallov
(Methods of Organometallic Chemistry. Types of
Organometallic Compounds Formed by Transition
Metals), Nesmeyanov, A.N. and Kocheshkov, K.A.,
Eds., Moscow: Nauka, 1975.
1
IR spectrum, cm : 3480, 3250 ( O H); 2966, 2830
(
C H); 1639 ( O H); 1385, 1312, 1255 (
and
C O
C H); 1242, 1222, 1178, 1135 (
and C H); 1118,
1016, 990, 954, 933, 904, 839 ( C O and C H); 772,
O H
724, 655, 604, 462, 457, 451, 441, 436, 426, 400
(
and C H).
C C
14. Plemenkov, V.V., Vvedenie v khimiyu prirodnykh
soedinenii (Introduction to the Chemistry of Natural
Compounds), Kazan: Mariiskii, 2001.
ACKNOWLEDGMENTS
This study was financially supported by the Rus-
15. Gusevskaya, E. and Gonsalves, J.A., J. Mol. Catal. A:
Chem., 1997, vol. 121, nos. 2 3, p. 131.
sian Foundation for Basic Research (project nos. 04-
03-32632a, 06-03-32137a), by the President of
the Russian Federation (project no. MK-3204. 2005.3),
and by the Government of St. Petersburg (project
no. PD05-1.3-20).
16. Gusevskaya, E.V., Quim. Nova, 2003, vol. 26, no. 2,
p. 242.
17. Syed, A., Stevens, E.D., and Cruz, S.G., Inorg. Chem.,
1984, vol. 23, no. 22, p. 3673.
REFERENCES
18. Goel, A.B., Goel, S., and Van Derveer, D., Inorg.
Chim. Acta, 1982, vol. 65, p. 205.
1. Lamotkin, A.I. and Klyuev, Yu.P., Respublikanskii
19. Wright, L.L., Wing, R.M., Rettig, M.F., and Wi-
ger, G.R., J. Am. Chem. Soc., 1980, vol. 102, no. 18,
p. 5949.
mezhvuzovskii sbornik: Khimiya
i khimicheskaya
tekhnologiya (Republican Interinstitution Collection:
Chemistry and Chemical Technology), Minsk:
Vysheishaya Shkola, 1982, no. 17, p. 99.
20. Bennett, M.A., Felixberger, J.K., and Willis, A.C.,
Gazz. Chim. Ital., 1993, vol. 123, p. 405.
2. Simonsen, J.L., The Terpenes, Cambridge: Cambridge
Univ., 1931, vol. 2.
21. Rodriquez i Zubiri, M., Slawin, A.M.Z., Wain-
wright, M., and Woollins, J.D., Polyhedron, 2002,
vol. 21, no. 17, p. 1729.
3. Barkhash, V.A. and Salakhutdinov, N.F., Usp. Khim.,
1997, vol. 66, no. 4, p. 376.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY Vol. 76 No. 8 2006