Inorganic Chemistry
Article
(4) Greenhouse Gas Sinks; Reay, D., Hewitt, C. N., Smith, K., Grace,
J., Eds.; CABI Books: Wallingford, U.K., 2007.
Conversion of CO2 to Cyclic Carbonate and Other Catalytic Abilities.
Chem. - Eur. J. 2016, 22, 3387−3396.
(5) Arakawa, H.; Armor, J. N.; Barteau, M. A.; Beckman, E. J.; Bell, A.
T.; Bercaw, J. E.; Creutz, C.; Dinjus, E.; Dixon, D. A.; Domen, K.;
Dubois, D. L.; Eckert, J.; Fujita, E.; Gibson, D. H.; Goddard, W. A.;
Goodman, D. W.; Keller, J.; Kubas, G. J.; Kung, H. H.; Lyons, J. E.;
Manzer, L. E.; Marks, T. J.; Morokuma, K.; Nicholas, K. M.; Periana,
R.; Que, L.; Rostrup-Nielson, J.; Sachtler, W. M. H.; Schmidt, L. D.;
Somorjai, G. A.; Stair, P. C.; Stults, B. R.; Tumas, W.; Aresta, M.; Sen,
A. Catalysis Research of Relevance to Carbon Management: Progress,
Challenges, and Opportunities. Chem. Rev. 2001, 101, 953−996.
(6) Darensbourg, D. J.; Holtcamp, M. W. Catalysts for the reactions
of epoxides and carbon dioxide. Coord. Chem. Rev. 1996, 153, 155−
174.
(7) Shaikh, A. A. G.; Sivaram, S. Organic Carbonates. Chem. Rev.
1996, 96, 951−976.
(8) Sakakura, T.; Kohno, K. The synthesis of organic carbonates from
carbon dioxide. Chem. Commun. 2009, 1312−1330.
(9) Gao, W. Y.; Chen, Y.; Niu, Y. H.; Williams, K.; Cash, L.; Perez, P.
J.; Wojtas, L.; Cai, J. F.; Chen, Y. S.; Ma, S. Q. Crystal Engineering of
an nbo Topology Metal−Organic Framework for Chemical Fixation of
CO2 under Ambient Conditions. Angew. Chem. 2014, 126, 2653−
2657.
(10) Haldar, R.; Reddy, S. K.; Suresh, V. M.; Mohapatra, S.;
Balasubramanian, S.; Maji, T. K. Flexible and Rigid Amine-Function-
alized Microporous Frameworks Based on Different Secondary
Building Units: Supramolecular Isomerism, Selective CO2 Capture,
and Catalysis. Chem. - Eur. J. 2014, 20, 4347−4356.
(11) Chakraborty, A.; Achari, A.; Eswaramoorthy, M.; Maji, T. K.
MOF−aminoclay composites for superior CO2 capture, separation and
enhanced catalytic activity in chemical fixation of CO2. Chem.
Commun. 2016, 52, 11378−11381.
(12) Yamaguchi, K.; Ebitani, K.; Yoshida, T.; Yoshida, H.; Kaneda, K.
Mg−Al Mixed Oxides as Highly Active Acid−Base Catalysts for
Cycloaddition of Carbon Dioxide to Epoxides. J. Am. Chem. Soc. 1999,
121, 4526−4527.
(13) Xie, Y.; Zhang, Z.; Jiang, T.; He, J.; Han, B.; Wu, T.; Ding, K.
CO2 Cycloaddition Reactions Catalyzed by an Ionic Liquid Grafted
onto a Highly Cross-Linked Polymer Matrix. Angew. Chem., Int. Ed.
2007, 46, 7255−7258.
(14) Srivastava, R.; Srinivas, D.; Ratnasamy, P. Zeolite-based
organic−inorganic hybrid catalysts for phosgene-free and solvent-free
synthesis of cyclic carbonates and carbamates at mild conditions
utilizing CO2. Appl. Catal., A 2005, 289, 128−134.
(15) Figueroa, J. D.; Fout, T.; Plasynski, S.; McIlvried, H.; Srivastava,
R. D. Advances in CO2 Capture Technology - The US Department of
Energy’s Carbon Sequestration Program. Int. J. Greenhouse Gas Control
2008, 2, 9−20.
(16) Chughtai, A. H.; Ahmad, N.; Younus, H. A.; Laypkov, A.;
Verpoort, F. Metal−organic frameworks: versatile heterogeneous
catalysts for efficient catalytic organic transformations. Chem. Soc.
Rev. 2015, 44, 6804−6849.
(17) Li, J.-R.; Ma, Y.; McCarthy, M. C.; Sculley, J.; Yu, J.; Jeong, H.-
K.; Balbuena, P. B.; Zhou, H.-C. Carbon dioxide capture-related gas
adsorption and separation in metal-organic frameworks. Coord. Chem.
Rev. 2011, 255, 1791−1823.
(18) Bae, Y.-S.; Snurr, R. Q. Development and Evaluation of Porous
Materials for Carbon Dioxide Separation and Capture. Angew. Chem.,
Int. Ed. 2011, 50, 11586−11596.
(22) Rovnyak, G. C.; Atwal, K. S.; Hedberg, A.; Kimball, S. D.;
Moreland, S.; Gougoutas, J. Z.; O’Reilly, B. C.; Schwartz, J.; Malley, M.
F. Dihydropyrimidine calcium channel blockers. 4. Basic 3-substituted-
4-aryl-1,4-dihydropyrimidine-5-carboxylic acid esters. Potent antihy-
pertensive agents. J. Med. Chem. 1992, 35, 3254−3263.
(23) Lewis, R. W.; Mabry, J.; Polisar, J. G.; Eagen, K. P.; Ganem, B.;
Hess, G. P. Dihydropyrimidinone positive modulation of delta-
subunit-containing gamma-aminobutyric acid type A receptors,
including an epilepsy-linked mutant variant. Biochemistry 2010, 49,
4841−4851.
(24) Dhumaskar, K. L.; Meena, S. N.; Ghadi, S. C.; Tilve, S. G.
Graphite catalyzed solvent free synthesis of dihydropyrimidin-2(1H)-
ones/thiones and their antidiabetic activity. Bioorg. Med. Chem. Lett.
2014, 24, 2897−2899.
(25) Chikhale, R.; Menghani, S.; Babu, R.; Bansode, R.; Bhargavi, G.;
Karodia, N.; Rajasekharan, M. V.; Paradkar, A.; Khedekar, P.
Development of selective DprE1 inhibitors: Design, synthesis, crystal
structure and antitubercular activity of benzothiazolylpyrimidine-5-
carboxamides. Eur. J. Med. Chem. 2015, 96, 30−46.
(26) Singh, K.; Kaur, T. Pyrimidine-based antimalarials: design
strategies and antiplasmodial effects. MedChemComm 2016, 7, 749−
768.
(27) Sheldrick, G. M. A short history of SHELX. Acta Crystallogr.,
Sect. A: Found. Crystallogr. 2008, 64, 112−122.
(28) Spek, A. L. Single-crystal structure validation with the program
PLATON. J. Appl. Crystallogr. 2003, 36, 7−13.
(29) An, J.; Farha, O. K.; Hupp, J. T.; Pohl, E.; Yeh, J. I.; Rosi, N. L.
metal-adeninate vertices for the construction of an exceptionally
porous metal-organic framework. Nat. Commun. 2012, 3, 604−609.
́
(30) Ferey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour,
J.; Surble, S.; Mirgiolaki, I. A Chromium Terephthalate-Based Solid
with Unusually Large Pore Volumes and Surface Area. Science 2005,
309, 2040−2042.
(31) Qian, J.; Jiang, F.; Zhang, L.; Su, K.; Pan, J.; Li, Q.; Yuan, D.;
Hong, M. Unusual pore structure and sorption behaviour in a
hexanodal zinc−organic framework material. Chem. Commun. 2014,
50, 1678−1681.
(32) Blatov, V. A.; Shevchenko, A. P.; Proserpio, D. M. Applied
Topological Analysis of Crystal Structures with the Program Package
ToposPro. Cryst. Growth Des. 2014, 14, 3576−3586.
(33) Wang, F.; Jing, X.; Zheng, B.; Li, G.; Zeng, G.; Huo, Q.; Liu, Y.
Four Cd-Based Metal−Organic Frameworks with Structural Varieties
Derived from the Replacement of Organic Linkers. Cryst. Growth Des.
2013, 13, 3522−3527.
(34) Medishetty, R.; Jung, D.; Song, X.; Kim, D.; Lee, S. S.; Lah, M.
S.; Vittal, J. J. Solvent-Induced Structural Dynamics in Non-
interpenetrating Porous Coordination Polymeric Networks. Inorg.
Chem. 2013, 52, 2951−2957.
(35) Chae, H. K.; Kim, J.; Friedrichs, O. D.; O’Keeffe, M.; Yaghi, O.
M. Design of Frameworks with Mixed Triangular and Octahedral
Building Blocks Exemplified by the Structure of [Zn4O(TCA)2]
Having the Pyrite Topology. Angew. Chem., Int. Ed. 2003, 42, 3907−
3909.
(36) Hou, L.; Liu, B.; Jia, L.-N.; Wei, L.; Wang, Y.-Y.; Shi, Q.-Z. Two
New (3,6)-Connected Frameworks Based on an Unsymmetrical
Tritopic Pyridyldicarboxylate Ligand and Co2 Dimer: Structures,
Magnetic, and Sorption Properties. Cryst. Growth Des. 2013, 13, 701−
707.
(37) Li, C.-P.; Chen, J.; Liu, P.-W.; Du, M. Structural diversity and
fluorescent properties of CdII coordination polymers with 5-
halonicotinates regulated by solvent and ligand halogen-substituting
effect. CrystEngComm 2013, 15, 9713−9721.
(38) Su, S.; Wang, S.; Song, X.; Song, S.; Qin, C.; Zhu, M.; Hao, Z.;
Zhao, S.; Zhang, H. Syntheses, structures, photoluminescence, and
magnetic properties of (3,6)- and 4-connected lanthanide metal−
organic frameworks with a semirigid tricarboxylate ligand. Dalton
Trans. 2012, 41, 4772−4779.
(19) Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.;
Bloch, E. D.; Herm, Z. R.; Bae, T.-H.; Long, J. R. Carbon Dioxide
Capture in Metal−Organic Frameworks. Chem. Rev. 2012, 112, 724−
781.
(20) Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent Metal−organic
Frameworks for Chemical Sensing and Explosive Detection. Chem. Soc.
Rev. 2014, 43, 5815−5840.
(21) De, D.; Pal, T. K.; Neogi, S.; Senthilkumar, S.; Das, D.; Gupta, S.
S.; Bharadwaj, P. K. A Versatile CuII Metal−Organic Framework
Exhibiting High Gas Storage Capacity with Selectivity for CO2:
F
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