SAKTHINATHAN ET AL.
9 of 10
[18] A. Umar, M. M. Rahman, S. H. Kim, Y. B. Hahn, Chem. Commun. 2008,
166.
200 μM hydrazine‐containing PBS. The results indicate the
excellent operational stability of the RGO/Pt‐TPP
nanocomposite.
[19] J. Wang, Z. Lu, Electroanalysis 1989, 1, 517.
[20] A. Krittayavathananon, P. Srimuk, S. Luanwuthi, M. Sawangphruk, Anal.
Chem. 2014, 86, 12272.
4
| CONCLUSIONS
[21] S. Park, J. An, J. R. Potts, A. Velamakanni, S. Murali, R. S. Ruoff, Carbon
2011, 49, 3019.
[22] J. Ping, Y. Wang, Y. Ying, J. Wu, Anal. Chem. 2012, 84, 3473.
In summary, we have successfully prepared a RGO/Pt‐TPP
nanocomposite using noncovalent π–π interaction. The pre-
pared nanocomposite was confirmed using SEM and UV,
FT‐IR and Raman spectroscopies. Electrochemical studies
were carried out using CV and the amperometric method.
The modified sensor exhibited a wide linear range from
13 nM to 232 μM with high sensitivity of 1.44 μA μM
−1 cm−2 and LOD of 5 nM. Moreover, the sensor performed
well even in the presence of 500‐fold excess concentration of
interfering molecules and ions. The practical feasibility of the
sensor was confirmed by determination of hydrazine in
ground water samples with good recoveries. The fabricated
sensor exhibited acceptable selectivity, stability, repeatability
and reproducibility. The excellent electrocatalytic activity of
the RGO/Pt‐TPP nanocomposite means that it can be
explored as an outstanding electrode material for the
detection of hydrazine.
[23] J. T. Robinson, F. K. Perkins, E. S. Snow, Z. Wei, P. E. Sheehan, Nano Lett.
2008, 10, 3137.
[24] P. D. Beer, M. G. B. Drew, R. J. Jagessar, Dalton Trans. 1997, 881.
[25] M. Biesaga, K. Pyrzynska, M. Trojanowicz, Talanta 2000, 51, 209.
[26] J. E. Falk, Porphyrins and Metalloporphyrins, Elsevier, New York 1975.
[27] A. Takai, C. P. Gros, J. M. Barbe, R. Guilard, S. Fukuzumi, Chem. – Eur. J.
2009, 15, 3110.
[28] L. Zheng, D. Ye, L. Xiong, J. Xu, K. Tao, Z. Zou, D. Huang, X. Kang, S.
Yang, J. Xia, Anal. Chim. Acta 2013, 768, 69.
[29] S. K. Lee, I. Okura, Anal. Commun. 1997a, 34, 185.
[30] S. K. Lee, I. Okura, Anal. Chim. Acta 1997b, 342, 181.
[31] R. R. D. Haas, R. P. M. V. Gijlswijk, E. B. Vandertol, J. M. A. A. Zijlmans,
T. B. Schut, J. Bonnet, N. P. Verwoerd, H. J. Tanke, J. Histochem. Cytochem.
1997, 45, 1279.
[32] H. Kunkely, A. Vogler, Inorg. Chim. Acta 1997, 254, 417.
[33] H. Brunner, K. M. Schellerer, B. Treittinger, Inorg. Chim. Acta 1997, 264, 67.
[34] A. Ferri, G. Polzonetti, S. Licoccia, R. Paolesse, D. Favretto, P. Traldi, M. V.
Russo, Dalton Trans. 1998, 4063.
[35] H. Yuan, L. Thomas, L. K. Woo, Inorg. Chem. 1996, 35, 2808.
ACKNOWLEDGMENTS
[36] H. P. Li, B. Zhou, Y. Lin, L. R. Gu, W. Wang, K. A. S. Fernando, S. Kumar,
The authors extend their appreciation to the International
Scientific Partnership Program ISPP at King Saud University
for funding this research work through ISPP#6. This project
was also supported by the National Science Council and
Ministry of Science and Technology, Taiwan (ROC).
L. F. Allard, Y. P. Sun, J. Am. Chem. Soc. 2004, 126, 1014.
[37] G. M. A. Rahman, D. M. Guldi, S. Campidelli, M. Prato, J. Mater. Chem.
2006, 16, 62.
[38] W. Zhang, A. U. Shaikh, E. Y. Tsui, T. M. Swager, Chem. Mater. 2009, 21,
3234.
[39] A. D. Adler, F. R. Longo, J. D. Finarelli, J. Goldmacher, J. Assour, L.
REFERENCES
Korsakoff, J. Org. Chem. 1967, 32, 476.
[1] R. Devasenathipathi, V. Mani, S. M. Chen, D. Arulraj, V. S. Vasantha,
[40] G. H. Barnett, M. F. Hudson, K. M. Smith, J. Chem. Soc. 1975, 14, 1401.
[41] W. S. Hummers, R. E. Offeman, J. Am. Chem. Soc. 1958, 80, 1339.
Electrochim. Acta 2014, 135, 260.
[2] S. Dutta, C. Ray, S. Mallick, S. Sarkar, A. Roy, T. Pal, RSC Adv. 2015, 5,
[42] C. He, Q. He, C. Deng, L. Shi, D. Zhu, Y. Fu, H. Cao, Chem. Commun.
2010, 46, 7536.
51690.
[3] J. Li, H. Xie, L. Chen, Sens. Actuators B 2011a, 153, 239.
[43] J. R. Sommer, A. H. Shelton, A. Parthasarathy, I. Ghiviriga, J. R. Reynolds,
[4] C. A. Pessoa, Y. Gushikem, S. Nakagaki, Electroanalysis 2002, 14, 15.
[5] Y. You, Y. Yang, Z. Yang, J. Solid State Electrochem. 2013, 17, 701.
K. S. Schanze, Chem. Mater. 2011, 23, 5296.
[44] Y. Guoa, X. Suna, Y. Liua, W. Wangb, H. Qiua, J. Gao, Carbon 2012, 50,
2513.
[6] Z. Zhao, Y. Sun, P. Li, S. Sang, W. Zhang, J. Hu, K. Lian, J. Electrochem.
Soc. 2014, 161, 157.
[45] A. Jorio, R. Saito, G. Dresselhaus, M. S. Dresselhaus, Raman Spectroscopy
in Graphene Related Systems, Wiley‐VCH, Weinheim 2011.
[7] R. Devasenathipathy, S. Palanisamy, S. M. Chen, C. Karuppiah, V. Mani, S. K.
Ramaraj, M. A. Ali, F. M. A. A. Hemaid, Electroanalysis 2015, 27, 1403.
[46] A. C. Ferrari, J. Robertson, Phys. Rev. B 2000, 61, 14095.
[8] US Environmental Protection Agency, Integrated risk information system
(IRIS) on hydrazine/hydrazine sulfate, National Center for Environmental
Assessment, Office of Research and Development, Washington, DC, 1999.
[47] P. Chen, O. S. Finikova, Z. Ou, S. A. Vinogradov, K. M. Kadish, Inorg.
Chem. 2012, 51, 6200.
[48] Z. Zhao, Y. Wang, P. Li, S. Sang, W. Zhang, J. Hu, K. Lian, Anal. Methods
2015, 7, 9040.
[9] A. Safavi, M. A. Karimi, Talanta 2002, 58, 785.
[10] G. W. Watt, J. D. Chrisp, J. Anal. Chem. 1952, 24, 2006.
[11] J. Budkuley, Microchim. Acta 1992, 108, 103.
[49] R. Madhu, B. Dinesh, S. M. Chen, R. Saraswathi, V. Mani, RSC Adv. 2015, 5
.54379
[12] S. Ikeda, H. Satake, Y. Kohri, Chem. Lett. 1984, 13, 873.
[13] M. Sun, L. Bai, D. Q. Liu, J. Pharm. Biomed. Anal. 2009, 49, 529.
[14] M. A. Koupparis, T. P. Hadjiioannou, Talanta 1978, 25, 477.
[15] A. M. Eibrashy, L. A. E. Hussein, Anal. Lett. 1997, 30, 609.
[50] H. R. Zare, Z. Sobhani, M. M. Ardakani, J. Solid State Electrochem. 2007,
11, 971.
[51] H. R. Zare, N. Nasirizadeh, Electrochim. Acta 2007, 52, 4153.
[52] Y. Liu, Y. Li, X. He, Anal. Chim. Acta 2014, 819, 26.
[53] S. Mutyala, J. Mathiyarasu, Sens. Actuators, B 2015, 210, 692.
[16] W. Siangproh, O. Chailapakul, R. Laocharoensuk, J. Wang, Talanta 2005,
67, 903.
[54] H. Ahmar, S. Keshipour, H. Hosseini, A. R. Fakhari, A. Shaabani, A.
[17] J. P. Liu, Y. Y. Li, J. Jiang, X. T. Huang, Dalton Trans. 2010, 39, 8693.
Bagheri, J. Electroanal. Chem. 2013, 690, 96.