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ChemComm
Page 4 of 5
DOI: 10.1039/C8CC01808A
COMMUNICATION
Journal Name
7
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A. Gómez-Suárez, D. J. Nelson, S. P. Nolan, Chem. Commun.
2017, 53, 2650.
For reviews on iron-catalysed Kumada reaction, see: (a) B. D.
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herein will aid in the rational design of NHC-based catalysts
and possibly inspire future research.
Table 2. Scope of the Fe(OTf)2/7Mes-catalysed cross-coupling reaction.
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a Yield determined by GC analysis. b 3 mol% 7Mes·HBr and 3 mol% NaOtBu were
used. c 5 mol% Fe(OTf)2, 15 mol% 7Mes·HBr and 15 mol% NaOtBu were used.
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Acknowledgements
The financial support for this work was provided by “GSK-EDB
Singapore Partnership for Green and Sustainable
Manufacturing” and the Institute of Chemical and Engineering
Sciences (ICES), Agency for Science, Technology and Research
(A*STAR), Singapore.
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30 The respective Au−NHC bond length in the solid structure
was used as the distance between the sphere center and
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value is slightly different from those from Nolan and Cavell,
who used 2.00 Å or 2.28 Å as fixed distance for the
metal−ligand bond.
4 | J. Name., 2012, 00, 1-3
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