Tetrahedron Letters p. 2481 - 2484 (1991)
Update date:2022-08-24
Topics:
Belkasmioui, Ahmed
Simonet, Jacques
Title compounds are electrochemically reduced into anion radicals of rather long lifetime. Surprisingly decomposition of such intermediates does not correspond as expected to a pure sulphur-carbon bond cleavage but mainly to a nucleophilic substitution toward the substrate. Nevertheless, cleavage reactions are observed in the case of methyl compounds.
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