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À
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3
H
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4
P [M ] 137.0009, found 137.0066. [
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1
1
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1
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.10. trans-(1S,2S)-1,2-Epoxypropylphosphonic acid 5
1
Procedure the same as for 1 (above) H NMR (300 MHz D
2
O) d:
3
3
1
1
.21 (m, 1H, J = 5.2, J = 3.3), 2.63 (dd, 1H, J = 21.4, J = 3.3), 1.36 (d,
1
3
H, J = 5.2); C NMR (300 MHz D
7.52.; HRMS (ESI) calcd
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2
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1
26, 12827–12832. and references therein.
À
C
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H
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2
2
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Acknowledgements
6. Choi, Y. H.; Choi, H. J.; Kim, D.; Uhm, K.; Kim, H. Appl. Microbiol. Biotechnol.
This work was supported by NSF-RUI grant CHE-0848708 from
the Organic and Macromolecular Chemistry Program and NSF-MRI
CHE-0923153. Additional support was provided by the NSF-STEP
Program under Award No. DUE-0856593. Any opinions, findings,
and conclusions or recommendations expressed in this material
are those of the author(s) and do not necessarily reflect the views
of the National Science Foundation. Additional thanks to Jon Stew-
art at the University of Florida for donating the enzyme library in
these studies.
2010, 87, 185–193.
2
2
2
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