Journal of the American Chemical Society p. 2516 - 2518 (1982)
Update date:2022-08-11
Topics:
Allen, Annette D.
Shahidi,, Fereidoon
Tidwell, Thomas T.
The reactivities of 1-cyano-1-ethoxyethylene (1) and 1-(trifluoromethyl)-1-ethoxypentene (2) in aqueous H2SO4 and D2SO4 have been measured.The kinetics and products establish the mechanism of these reactions as rate-limiting protonation on the double bond.The observed rates are predicted with surprising accuracy by the previously introduced correlation logkH+ = -10.5Σp+ - 8.92.
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