PREPARATION AND SPECTRAL PROPERTIES OF β-BROMO-SUBSTITUTED
1135
1
Yield 0.018 g (0.0256 mmol, 80%), Rf 0.76. Н NMR
ACKNOWLEDGMENTS
spectrum, δ, ppm: 8.30 br.s (16Н, Нo,m, С6Н5), 7.75
br.s (4Н, Нp, С6Н5). Found, %: С 74.95; Н 3.94; N
7.88. C44H28ClMnN4. Calculated, %: С 75.16; Н 4.01;
N 7.97.
This work was financially supported by Russian
Scientific Foundation, project no. 14-13-00232.
REFERENCES
(Cl)Mn(III) porphyrinates V and VI were prepared
similarly.
1. Rumyantsev, E.V., Antina, E.V., and Chistyakov, Yu.V.,
Khimicheskie osnovy zhizni (The Chemical Basis of
Life), Moscow: Khimiya, Koloss, 2007.
2. Valentine, J.S. and Quinn, A.E., Inorg. Chem.
Commun., 1976, vol. 15, no. 8, p. 1997.
3. Сamerzind, M.J., Hollander, F.J., and Hill, C.L., Inorg.
Chem., 1983, vol. 22, no. 25, p. 3776.
4. Stuzhin, P.A., Repina, N.V., Klyueva, M.E., and
Fedotova, E.V., Russ. J. Phys. Chem., 2004, vol. 78,
no. 6, p. 864.
2-Bromo-5,10,15,20-tetraphenylporphyrinato-
chloridomanganese(III) (V). a. Prepared from 0.02 g
(0.0288 mmol) of compound II and 0.072 g (0.576 mmol)
of MnCl2; reaction duration 65 min. Yield 0.0176 g
(0.0225 mmol, 78%), Rf 0.78.
b. Prepared from 0.02 g (0.0288 mmol) of com-
pound II, 0.053 g (0.288 mmol) of CdCl2, and 0.072 g
(0.576 mmol) of MnCl2; reaction duration 25 min.
5. Boucher, L.J., Coord. Chem. Rev., 1972, vol. 7, no. 3,
p. 289. DOI: 10.1016/S0010-8545(00)80024-7.
1
Yield 0.018 g (0.0230 mmol, 80%), Rf 0.78. Н NMR
6. Doro, F.G., Lindsay Smith, J.R., Ferreira, A.G., and
Assis, M.D., J. Mol. Catal. (A), 2000, vol. 164, p. 97.
DOI: 10.1016/S1381-1169(00)00352-6.
7. Lembo, A., Tagliatesta, P., and Guldi, D.M., J. Phys.
Chem. (A), 2006, vol. 110, no. 40, p. 11424. DOI:
10.1021/jp062735h.
spectrum, δ, ppm: 8.20 br.s (16Н, Нo,m, С6Н5), 7.55
br.s (4Н, Нp, С6Н5). Found, %: С 67.41; H 3.42; N
10.15. C44H27BrСlMnN4. Calculated, %: C 67.58; H
3.48; N 10.22.
8. Kumar, P.K., Bhyrappa, P., and Varghese, B., Tetra-
hedron Lett., 2003, vol. 44, p. 4849. DOI: 10.1016/
S004039(03)01143-2.
9. Koordinatsionnye soedineniya porfirinov i ftalotsianina
(Coordination Compounds of Porphyrin and Phthalo-
cyanine), Moscow: Nauka, 1978.
2,3,12,13-Tetrabromo-5,10,15,20-tetraphenyl-
porphyrinatochloridomanganese(III) (VI). a.
Prepared from 0.02 g (0.0215 mmol) of compound III
and 0.054 g (0.430 mmol) of MnCl2; reaction duration
2.5 h. Yield 0.0166 g (0.0163 mmol, 76%), Rf 0.82.
10. Zvezdina, S.V., Kulikova, O.M., and Mamardashvili, N.Zh.,
Russ. J. Gen. Chem., 2013, vol. 83, no. 11, p. 2103.
DOI: 10.1134/S107036213110248.
11. Buchler, J.W., Drecher, C., and Lay, K.L., Z. Natur-
forsch. (В), 1982, vol. 37, p. 1155.
12. Zvezdina, S.V. Chizhova, N.V., and Mamardashvili, N.Zh.,
Russ J. Gen. Chem., 2014, vol. 84, no. 7, p. 1389. DOI:
10.1134/S1070363214070251.
b. Prepared from 0.02 g (0.0215 mmol) of comound
III, 0.039 g (0.215 mmol) of CdCl2, and 0.054 g
(0.430 mmol) of MnCl2; reaction duration 45 min.
1
Yield 0.017 g (0.0167 mmol, 79%), Rf 0.72. Н NMR
spectrum, δ, ppm: 8.67 br.s (16Н, Нo,m, С6Н5), 8.05
br.s (4Н, Нp, С6Н5). Found, %: С 51.72; Н 2.34; N 5.41.
C44Н24N4СlBr4Mn. Calculated, %: С 51.88; Н 2.38; N 5.50.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY Vol. 85 No. 5 2015