manganese tetraphenylporphyrin

Base Information

• Chemical Name: manganese tetraphenylporphyrin
• CAS No.: 31004-82-7
• Molecular Formula: C44H28 Mn N4
• Molecular Weight: 667.671
• Mol file: 31004-82-7.mol

Synonyms:Manganese,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-;Manganese, [5,10,15,20-tetraphenylporphinato(2-)]- (8CI); 21H,23H-Porphine,5,10,15,20-tetraphenyl-, manganese complex; (Tetraphenylporphinato)manganese;(meso-Tetraphenylporphinato)manganese; Manganesemeso-5,10,15,20-Tetraphenylporphyrin; Manganese meso-tetraphenylporphine;Manganese meso-tetraphenylporphyrin; Manganese tetraphenylporphine;Manganese(II) tetraphenylporphine; Manganese(II) tetraphenylporphyrin;[5,10,15,20-Tetraphenylporphinato(2-)]manganese

Chemical Property of manganese tetraphenylporphyrin

Chemical Property:

• PSA: 56.30000
• LogP: 7.47210

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of manganese tetraphenylporphyrin

There total 47 articles about manganese tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) → manganese(II) 5,10,15,20-tetraphenylporphyrinate (31004-82-7)

Guidance literature:

In solid; High Pressure; 2000 MPa at room temp.; extrd. (chloroform), chromy. (alumina); UV;

Reference yield: 65.0%

azidomanganese(III) meso-tetraphenylporphyrin (56413-47-9) → manganese(II) 5,10,15,20-tetraphenylporphyrinate (31004-82-7) + nitridomanganese(V) meso-tetraphenylporphyrinate (83632-54-6)

Guidance literature:

In solid; byproducts: N2; heating, 250 ° C, 5h, 1E-3 to 1E-5 Torr; chromy. (Al2O3, CH2Cl2, 30% EtOH-C6H6), recrystn. (C6H6-hexane), drying (150 ° C, vac.), elem. anal.;

DOI:10.1246/cl.1988.261

Reference yield:

2,3-Dimethylaniline (87-59-2) → 2-amino-4,5-dimethylbenzothiazole (79050-49-0)

Guidance literature:

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

manganese(II) acetate

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

sodium tetrahydroborate

Downstream raw materials:

manganese(III) tetraphenylporphyrinate

manganese(II) meso-tetraphenylporphyrinate mononitrosyl complex

nitritomanganese(III) tetraphenylporphyrin

dinitrogen monoxide

Refernces

• 1、 Shimizu,Orita,Hayakawa,Takehira. "Aromatic olefin oxygenation with tetrahydroborate and dioxygen catalyzed by a manganese porphyrin". . p. 165 - 172. Retrieved 1989.
• 2、 Hoshino, Mikio,Konishi, Shiro. "". . p. 511 - 514. Retrieved 1985.
• 3、 Willner, Itamar,Otvos, John W.,Calvin, Melvin. "Preparation of an Oxoporphyrinatomanganese(IV) Complex". . p. 964 - 965. Retrieved 1980.
• 4、 Meininger, Daniel J.,Kasrawi, Zieph,Arman, Hadi D.,Tonzetich, Zachary J.. "Synthesis of tetraphenylporphyrinate manganese(III) siloxides by silyl group transfer from silanethiols". . p. 1970 - 1978. Retrieved 2016.
• 5、 Rao, Ramakrishna,Symons, Martyn C. R.,Harriman, Anthony. "Formation of Manganese(II) Porphyrin Derivatives from Manganese(III) Derivatives by Ionizing Radiation". . p. 3393 - 3396. Retrieved 1982.
• 6、 Suzuki, Toru,Imamura, Taira,Fujimoto, Masatoshi. "Facile Preparation of Manganese(II) Tetraphenylporphyrin by the Pyrolysis of Dimethoxomanganese(IV) Tetraphenylporphyrin". . p. 257 - 260. Retrieved 1988.
• 7、 Shen, Hai M.,Ye, Hong L.,Wang, Qin,Hu, Meng Y.,Liu, Lei,She, Yuan B.. "Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins". . p. 314 - 322. Retrieved 2021/04/09.
• 8、 Chattopadhyay, Buddhadeb,Das, Sandip Kumar,Khatua, Hillol,Roy, Satyajit. "Dual Reactivity of 1,2,3,4-Tetrazole: Manganese-Catalyzed Click Reaction and Denitrogenative Annulation". supporting information. p. 304 - 312. Retrieved 2020/10/29.