5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride

Base Information

• Chemical Name: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride
• CAS No.: 34557-72-7
• Molecular Formula: C₄₄H₂₈ClMnN₄
• Molecular Weight: 703.124
• Mol file: 34557-72-7.mol

Synonyms:

Chemical Property of 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride

There total 31 articles about 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

manganese(II) chloride tetrahydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4)

Guidance literature:

In N,N-dimethyl-formamide; at 150 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b03184

Reference yield: 85.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + manganese(II) chloride tetrahydrate → 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride (32195-55-4,34557-72-7)

Guidance literature:

In N,N-dimethyl-formamide; soln. stirred at 100°C for 3 h; monitored by chromy.; solvent removed (vac.); purifn. on silica gel using CHCl3 as eluent;

DOI:10.1016/S0020-1693(00)00360-1

Reference yield: 80.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) + manganese(ll) chloride (7773-01-5) → (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4)

Guidance literature:

With cadmium(II) chloride; In N,N-dimethyl-formamide; for 0.333333h; Reflux;

DOI:10.1134/S1070363215050217

upstream raw materials:

azidomanganese(III) meso-tetraphenylporphyrin

1-Chloronaphthalene

5,10,15,20-tetraphenyl-21H,23H-porphine

[ClMn(meso-tetraphenylporphinato)(OIPh)]2O

Downstream raw materials:

{Mn(O)(tetraphenylporphyrin^(2-))}

lauric acid

ClMn(IV)(O)(tetraphenylporphyrin)

manganese(II) tetraphenylporphyrinate

Refernces

• 1、 Bhuvanesh, Nattamai,Das, Anuvab,Figgins, Matthew T.,Hicks, Madeline H.,Ozarowski, Andrew,Powers, David C.,Reid, Kaleb A.,Telser, Joshua,Van Trieste, Gerard P.. "Nitrene Photochemistry of Manganese N-Haloamides**". supporting information. p. 26647 - 26655. Retrieved 2021/11/18.
• 2、 -. "Method for synthesizing tetraaryl manganese porphyrin through synchronous aldehyde and pyrrole condensation and bivalent manganese salt oxidation insertion reaction". Paragraph 0028-0029. . Retrieved 2020/09/08.