azidomanganese(III) meso-tetraphenylporphyrin

Base Information

• Chemical Name: azidomanganese(III) meso-tetraphenylporphyrin
• CAS No.: 56413-47-9
• Molecular Formula: C₄₄H₂₈MnN₇
• Molecular Weight: 709.691
• Mol file: 56413-47-9.mol

Synonyms:azidomanganese(III) meso-tetraphenylporphyrin

Chemical Property of azidomanganese(III) meso-tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of azidomanganese(III) meso-tetraphenylporphyrin

There total 4 articles about azidomanganese(III) meso-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

hydrogen azide (7782-79-8) + aquahydroxo(tetraphenylporphinato)manganese(III) → tetraphenylporphinatomanganese(III) azide (56413-47-9)

Guidance literature:

In benzene; addn. of benzene soln. of HN3 to soln. of Mn complex, stirring, 1 h; mixt. allowed to stand for 24 h; evapn. of solvent in vac., crystg. from acetone, drying in high vac. at40°C;

Reference yield:

sodium azide + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) → tetraphenylporphinatomanganese(III) azide (56413-47-9)

Guidance literature:

In N,N-dimethyl-formamide; porphyrin and 2- to 20-fold excess of Mn(AcO)2 were added to DMF, refluxed (or heated in bomb to reflux temp.) for ca. 5 h, solvent removed by high-vac. rotary evapn., extd. with mixt. of NaN3-H2O/CHCl3 by shaking for several min; aq. phase sepd., solvent removed by rotary evapn.;

DOI:10.1021/ja00323a036

Reference yield:

diazido(5,10,15,20-tetraphenylporphinato)manganese(IV)*0.29CH2Cl2 (87337-87-9) → tetraphenylporphinatomanganese(III) azide (56413-47-9)

Guidance literature:

In dichloromethane; Mn-complex dissolved in CH2Cl2; monitored by UV-vis spectra;

upstream raw materials:

manganese(III) meso-tetraphenylporphyrin acetate

5,10,15,20-tetraphenyl-21H,23H-porphine

manganese(II) acetate

hydrogen azide

Downstream raw materials:

[N₃Mn(meso-tetraphenylporphinato)]2O

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

Mn(C₄₄H₂₈N₄)(N₄CCHCHCN)

Mn(C₄₄H₂₈N₄)(N₄CC₆H₅)

Refernces

• 1、 Powell, Michael F.,Pai, Emil F.,Bruice, Thomas C.. "Study of (Tetraphenylporphinato)manganese(III)-Catalyzed Epoxidation and Demethylation Using p-Cyano-N,N-dimethylaniline N-Oxide as Oxygen Donor in a Homogeneous System. Kinetics, Radiochemical Ligation Studies, and Reaction Mechanism for a Model of Cytochrome P-450". . p. 3277 - 3285. Retrieved 2007/10/02.
• 2、 Camenzind, Mark J.,Hollander, Frederick J.,Hill, Craig L.. "Synthesis, characterization, and ground electronic state of the unstable monomeric manganese(IV) porphyrin complexes diazido- and bis(isocyanato)(5,10,15,20-tetraphenylporphinato)manganese(IV). Crystal and molecular structure of the bis(isocyanato) complex". . p. 3776 - 3784. Retrieved 2008/10/08.