CID 15977210

Base Information

• Chemical Name: CID 15977210
• CAS No.: 58356-65-3
• Molecular Formula: C46H32MnN4O2
• Molecular Weight: 726.716
• European Community (EC) Number: 676-581-5
• DSSTox Substance ID: DTXSID60657615
• Mol file: 58356-65-3.mol

Synonyms:58356-65-3;DTXSID60657615;Manganese(2+) 5,10,15,20-tetraphenylporphine-21,23-diide--acetic acid (1/1/1)

Chemical Property of CID 15977210

Chemical Property:

• Refractive Index: ">
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 71.88000
• Density: g/cm³
• LogP: 6.52870
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 727.190569
• Heavy Atom Count: 53
• Complexity: 838

Purity/Quality:

98%Min ^*data from raw suppliers

Mn(III)meso-TetraphenylporphineAcetate(1-3%chlorin) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O.C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)[N-]3.[Mn+2]

Technology Process of CID 15977210

There total 11 articles about CID 15977210 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → manganese(III) meso-tetraphenylporphyrin acetate (58356-65-3)

Guidance literature:

With sodium acetate; In acetic acid; for 3h; Reflux; Inert atmosphere;

DOI:10.1016/j.ultsonch.2011.10.007

Reference yield: 96.0%

3Mn(3+)*O(2-)*7O2CCH3(1-)*3H2O = [Mn3O(OCOCH3)7]*3H2O + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → manganese(III) meso-tetraphenylporphyrin acetate (58356-65-3)

Guidance literature:

With sodium acetate; potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150 ℃;

DOI:10.1016/j.poly.2012.05.038

Reference yield: 96.0%

manganese(III) acetate trihydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → [MnIII(TPP)(OAc)] (58356-65-3)

Guidance literature:

With sodium acetate; potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150 ℃;

upstream raw materials:

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

5,10,15,20-tetraphenyl-21H,23H-porphine

manganese (II) acetate tetrahydrate

manganese(II) acetate

Downstream raw materials:

5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride

dimethoxomanganese(IV) tetraphenylporphyrin

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

manganese(II) 5,10,15,20-tetraphenylporphyrinate

Refernces

• 1、 Esfandiar, Milad,Saadati, Saeedeh. "Partial and full β-bromination of meso-tetraphenylporphyrin: Effects on the catalytic activity of the manganese and nickel complexes for photo oxidation of styrene in the presence of molecular oxygen and visible light". . . Retrieved 2020/08/17.
• 2、 Yao, Shu A.,Hansen, Christopher B.,Berry, John F.. "A convenient, high-yielding, chromatography-free method for the insertion of transition metal acetates into porphyrins". . p. 2 - 6. Retrieved 2013/07/26.