nitridomanganese(V) meso-tetraphenylporphyrinate

Base Information

• Chemical Name: nitridomanganese(V) meso-tetraphenylporphyrinate
• CAS No.: 83632-54-6
• Molecular Formula: C₄₄H₂₈MnN₅
• Molecular Weight: 681.678
• Mol file: 83632-54-6.mol

Synonyms:nitridomanganese(V) meso-tetraphenylporphyrinate

Chemical Property of nitridomanganese(V) meso-tetraphenylporphyrinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nitridomanganese(V) meso-tetraphenylporphyrinate

There total 6 articles about nitridomanganese(V) meso-tetraphenylporphyrinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4) + ammonia (7664-41-7) → nitridomanganese(V) meso-tetraphenylporphyrinate (83632-54-6)

Guidance literature:

With chlorine; In chloroform; satn. of chloroform soln. of porphin deriv. with gaseous ammonia at -20°C, bubbling chlorine through the resulting soln. for 10 min; filtration, chromy. (neutral Al2O3, CH2Cl2); elem. anal.;

Reference yield: 65.0%

azidomanganese(III) meso-tetraphenylporphyrin (56413-47-9) → manganese(II) 5,10,15,20-tetraphenylporphyrinate (31004-82-7) + nitridomanganese(V) meso-tetraphenylporphyrinate (83632-54-6)

Guidance literature:

In solid; byproducts: N2; heating, 250 ° C, 5h, 1E-3 to 1E-5 Torr; chromy. (Al2O3, CH2Cl2, 30% EtOH-C6H6), recrystn. (C6H6-hexane), drying (150 ° C, vac.), elem. anal.;

DOI:10.1246/cl.1988.261

Reference yield:

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4) → nitridomanganese(V) meso-tetraphenylporphyrinate (83632-54-6)

Guidance literature:

With iodosylbenzene; ammonia; In dichloromethane; Mn-compd. added to degassed CH2Cl2 contg. NH3 under Ar, ca. 13 equiv ofiodosylbenzene and NH3 added dropwise over 15 min, stirred for 30 min; recrystd. from toluene-hexane;

DOI:10.1021/ja00389a072

upstream raw materials:

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

ammonia

azidomanganese(III) meso-tetraphenylporphyrin

bromo(5,10,15,20-tetraphenylporphyrinato)manganese(III)

Downstream raw materials:

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

manganese(III) meso-tetraphenylporphyrin acetate

chloro(5,10,15,20-tetraphenylporphyrinato)chromium(III)

nitridomanganese(V) octaethylporphyrinate

Refernces

• 1、 Hill, Craig L.,Hollander, Frederick J.. "". . p. 7318 - 7319. Retrieved 1982.
• 2、 Imamura, Taira,Yamamoto, Yuichi,Suzuki, Toru,Fujimoto, Masatoshi. "Competitive Photochemical Reactions of Azidomanganese(III) Tetraphenylporphyrin in 2-Methyltetrahydrofuran". . p. 2185 - 2186. Retrieved 2007/10/02.