Synthesis p. 350 - 352 (1991)
Update date:2022-08-17
Topics:
Astorga
Rebolledo
Gotor
Amano PS lipase catalyzes the reaction of formic hydrazide, acetic hydrazide and methyl carbazate with various esters: α,β-unsaturated hydrazides were obtained by using methyl acrylate or vinyl crotonate. The reaction with ethyl (±)-2-chloropropionate yields the corresponding hydrazide in good yield but with moderate enantiomeric excess.
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(1981)Doi:10.1071/CH14080
(2014)