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It was demonstrated that narrowly size-distributed SiNPs with
average diameters less than 100 nm could be surface-decorated
with ATRP initiation sites, while retaining their high dispersi-
bility in solution. Surface-initiated ATRP of MMA using these
functionalized SiNPs proceeded in a living fashion, yielding
structurally controlled hybrid nanoparticles with a SiNP core
and a shell of variable thickness composed of well-defined,
concentrated PMMA brushes. Thanks to their exceptionally
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€
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Acknowledgment. This work was supported in part by a
Grant-in-Aid for Scientific Research (Grant-in-Aid 17685010)
from the Ministry of Education, Culture, Sports, Science, and
Technology, Japan, and by the Industrial Technology Research
Grant Program in 2004 and 2009 from the New Energy and
Industrial Technology Development Organization (NEDO) of
Japan. We thank Chisso Corporation for their kind donation of
tetraethoxysilane and triethoxysilane.
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