Journal of Fluorine Chemistry p. 91 - 94 (1994)
Update date:2022-08-17
Topics:
Dorra, Michael
Haas, Alois
Irradiation of bis(trifluoromethylsulfanyl)ketene (2) with UV light in an Ar matrix at 10 K produces CO, CS2 and C2F6, which have been identified by infrared spectroscopy and interpreted as the decomposition products of bis(trifluoromethylsulfanyl)carbene (1).Irradiation of 2 in n-hexane at 283 K provides the bis(trifluoromethylsulfanyl)methyl radical (3) as an unstable intermediate by ESR spectroscopy.If 2 is irradiated neat or in C6F6 solution, small yields of (CF3S)2C=C(SCF3)2 (5) are obtained.The formation of 3 from 1 is discussed.
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