421-17-0Relevant articles and documents
Bis(trifluormethylsulfanyl)carben (CF3S)2C:; Generierung und Nachweis
Dorra, Michael,Haas, Alois
, p. 91 - 94 (1994)
Irradiation of bis(trifluoromethylsulfanyl)ketene (2) with UV light in an Ar matrix at 10 K produces CO, CS2 and C2F6, which have been identified by infrared spectroscopy and interpreted as the decomposition products of bis(trifluoromethylsulfanyl)carbene (1).Irradiation of 2 in n-hexane at 283 K provides the bis(trifluoromethylsulfanyl)methyl radical (3) as an unstable intermediate by ESR spectroscopy.If 2 is irradiated neat or in C6F6 solution, small yields of (CF3S)2C=C(SCF3)2 (5) are obtained.The formation of 3 from 1 is discussed.
METHOD FOR PREPARATION OF PERFLUOROALKYL SULFENYL CHLORIDE
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Page/Page column 9, (2012/12/13)
The present disclosure provides a process for the preparation of perfluoroalkyl sulfenyl chloride by reacting a compound of formula [I] with at least one fluoride compound and thiophosgene.
PROCESS FOR SYNTHESIS OF FIPRONIL
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Page/Page column 22-23, (2011/10/03)
A process for preparation of a trifluoromethylsulfinyl pyrazole compound of formula (I) from a compound of formula (III) is provided, wherein R, R1 and R2 represent a group containing halogen respectively and R3 represents a perhaloalkyl.