374-10-7Relevant articles and documents
BEITRAEGE ZUR CHEMIE DER SCHEFELHALOGENIDE 15. DICHLOR-FLUOR-TRIFLUOROMETHYLSULFURAN, CF3SCl2F
Minkwitz, Rolf,Nass, Ulrike
, p. 393 - 398 (2007/10/02)
The preparation of the sulfurane CF3SCl2F is reported.Upon sublimation of the sulfonium salt CF3SCl2+AsF6- the compounds CF3SCl2F and AsF5 coexist in the gaseous phase.After trapping AsF5 as KAsF6 extremely instable CF3SCl2F is isolated and characterised by IR-, Raman- and 19F-NMR-spectroscopy.