1
276ꢀꢀꢀꢀꢁꢀE. Hobbollahi et al.: Synthesis, crystal structures and blue emission of zinc(II) halide complexes
−
1
(
548.65 g mol ): calcd. C 43.70, H 5.13, N 10.19; found:
[3] M. Laitaoja, J. Valjakka, J. Jänis, Inorg. Chem. 201ꢄ, 52,
0983.
1
C 43.90, H 5.13, N 9.96. – ESI-MS (MeOH): m/zꢀ=ꢀ195.14
[
[
4] G. Parkin, Chem. Rev. 200ꢅ, 104, 699.
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[6] K. A. Mccall, C. Huang, C. A. Fierke, J. Nutr. 2000, 130, 143ꢎS.
[ꢎ] D. Magda, P. Lecane, Z. Wang, W. Hu, P. Thiemann, X. Ma, P. K.
Dranchak, X. Wang, V. Lynch, W. Wei, V. Csokai, J. G. Hacia, J. L.
Sessler, Cancer Res. 200ꢇ, 68, 5318.
+
+
[
[
[
1
L+MeOH], 257.06 [LZn+MeOH] , 325.23 [LZnBr] , 405.16
+
+
+
LZnBr +H O] , 469.07 [L ZnBr] , 631.19 [L ZnBr] , 713.11
2
2
2
3
+
1
L ZnBr ] . – H NMR (DMSO, 300 MHz): δꢀ=ꢀ1.54 (m, 2H),
3
2
.81 (m, 2H), 2.06 (s, 6H), 2.21 (m, 4H), 3.14 (m, 4H), 7.44
m, 2H), 7.82 (dt, 2H), 8.47 (dd, 2H), 8.52 (d, 2H).
(
[
[
8] G. Parkin, Chem. Commun. 2000, 19ꢎ1.
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[
[
[
[
10] E. S. Donovan, B. M. Barry, C. A. Larsen, M. N. Wirtz, W. E.
Geiger, R. A. Kemp, Chem. Commun. 2016, 52, 1685.
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Nucl.Chem. 1ꢈ7ꢇ, 40, 143.
ꢅ.1ꢄ Bis((–)-nicotine)-diiodido-zinc(II), ꢅ-I
(
0.5 g, 1.56 mmol) ZnI , (–)-nicotine (0.50 g, 3.1 mmol).
2
12] C. Pettinari, F. Marchetti, A. Cingolani, S. I. Troyanov, A.
Drozdov, Polyhedron 1ꢈꢈꢇ, 17, 16ꢎꢎ.
Yield: 0.65 g (65%). – Elemental analysis for C H N ZnI
2
0
28
4
2
−1
(
643.63 g mol ): calcd. C 37.32, H 4.38, N 8.70; found:
13] D.M.L. Goodgame, M. Goodgame, G.W. Rayner-Canham, Inorg.
Chim. Acta 1ꢈ6ꢈ, 3, 399.
C 37.81, H 4.44, N 8.51. – ESI-MS (MeOH): m/zꢀ=ꢀ257.06
+
+
+
+
[
LZn+MeOH] , 352.94 [LZnI] , 515.06 [L ZnI] , 677.17 [L ZnI] ,
2
3
[14] D. M. L. Goodgame, M. Goodgame, G. W. Rayner-Canham,
+
1
8
05.09 [L ZnI ] . – H NMR (DMSO, 300 MHz): δꢀ=ꢀ1.58 (m,
Inorg. Chim. Acta 1ꢈ6ꢈ, 3, 406.
3
2
[
15] P. Drożdżewski, B. Pawlak, T. Głowiak, Polyhedron 2002, 21,
2
H), 1.81 (m, 4H), 2.07 (s, 6H), 2.29 (m, 4H), 3.13 (m, 4H),
2
819.
7.39 (m, 2H), 7.70 (dt, 2H), 8.45 (dd, 2H), 8.49 (d, 2H).
[
[
16] G. Musie, X. Li, D. R. Powell, Acta Crystallogr. 200ꢅ, E60, m4ꢎ1.
1ꢎ] S. G. Baca, I. G. Filippova, N. V. Gerbeleu, Y. A. Simonov, M.
Gdaniec, G. A. Timco, O. A. Gherco, Y. L. Malaestean, Inorg.
Chim. Acta 200ꢄ, 344, 109.
ꢅ.1ꢅ Crystal structure determinations
[
18] P. K. Bharadwaj, H. J. Schugar, J. A. Potenza, Acta Crystallogr.
1ꢈꢈ1, C47, ꢎ54.
Single-crystal structure analyses was carried out on a
Bruker SMART APEX and Bruker SMART X2S diffrac-
tometer with graphite-monochromatized MoKα radia-
tion (λꢀ=ꢀ0.71073 Å). The structures were solved by Direct
Methods (Sꢁꢂꢃꢄꢅ-9 7, Sꢆꢇ-97) [50, 51] and refined by full-
[
[
19] H. Haendler, Acta Crystallogr. 1ꢈꢈ0, C46, 2054.
20] M. Strickler, B. M. Goldstein, K. Maxfield, L. Shireman, G. Kim,
D. S. Matteson, J. P. Jones, Biochem. 200ꢄ, 42, 11943.
21] M. O. Onani, R. A. Lalancette, N. T. Muriithi, E. A. Nyawade, B.
V. Kgarebe, Acta Crystallogr. 2010, E66, m480.
[
2
[22] J. Guan, R. D. Fischer, Eur. J. Inorg. Chem. 2001, 249ꢎ.
[
[
matrix least-squares on F (Sꢁꢂꢃꢄꢃ-97) [52]. The H atoms
23] Z. Jiang, G. Tang, L. Lu, Acta Crystallogr. 200ꢇ, E64, m958.
24] T. Kawasaki, T. Nishimura, T. Kitazawa, Bull. Chem. Soc. Japan
were calculated geometrically, and a riding model was
applied in the refinement process. Tables 2 and 3 summa-
rize the most important crystallographic data.
2
010, 83, 1528.
[
25] S. Michalik, R. Kruszynski, K. Leszczyńska-Sejda, J. Kusz, S.
CCDC 1495476–1495485 contain the supplementary
Krompiec, J. Coord. Chem. 200ꢈ, 62, 1232.
crystallographic data for 1-Br, 1-I, 2-Cl, 2-Br, 2-I, 3-Br, 3-I, [26] F.M. Albertí, J.J. Fiol, A. García-Raso, M. Torres, A. Terrón, M.
Barceló-Oliver, M. J. Prieto, V. Moreno, E. Molins, Polyhedron
4
-Cl, 4-Brand 4-I, respectively. These datacan be obtained
2
010, 29, 34.
2ꢎ] O. Filevich, M. Salierno, R. Etchenique, J. Inorg. Biochem. 2010,
04, 1248.
[
[
[
[
[
1
28] S. Jana, P. A. G. Cormack, A. R. Kennedy, D. C. Sherrington,
J. Mater. Chem. 200ꢈ, 19, 342ꢎ.
Acknowledgment: We thank the JKU and Prof. Günther
Knör (JKU) for his generous support of the experimental
work. The NMR spectrometers were acquired in collabora-
tion with the University of South Bohemia (CZ) with finan-
cial support from the European Union through the EFRE
INTERREG IV ETC-AT-CZ programme (project M00146,
29] C. Hirtenlehner, U. Monkowius, Inorg. Chem. Commun. 2012,
1
5, 109.
30] Z.-J. Jiang, Y. Zhang, G.-D. Tang, J.-Y. Zhao, L.-D. Lu, Z. Kristal-
logr. NCS 200ꢈ, 224, 466.
31] G. Meyer, A. Berners, I. Pantenburg, Z. Anorg. Allg. Chem.
2006, 632, 34.
“RERI-uasb”).
[32] M. R. Udupa, B. Krebs, Inorg. Chim. Acta 1ꢈꢇ0, 40, 161.
[
33] Z.-J. Jiang, L.-T. An, J. Song, L.-D. Lu, Lu-De, Wuji Huaxue Xuebao
Chin. J. Inorg. Chem.) 2012, 28, 35.
(
[
[
34] W. Lewis, P. J. Steel, Supramol. Chem. 2005, 17, 5ꢎ9.
35] Z. Jiang, G. Tang, Y. Zhang, J. Zhao, Acta Crystallogr. 200ꢇ, E64,
m1319.
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