Paper
Green Chemistry
traditional solvents in harsh conditions, demonstrated by a
comparison with ethyl acetate and MEK. Importantly, each of
the four candidates can be synthesised via a catalytic route
from potentially renewable resources, thus enhancing their
green credentials. Overall, these esters and ketones of low
polarity and volatility provide several options for industry for
the replacement of hazardous VNP solvents for a range of
processes.
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Conflicts of interest
11 S. Jin, F. Byrne, C. R. McElroy, J. Sherwood, J. H. Clark and
A. J. Hunt, Faraday Discuss., 2017, 202, 157–173.
There are no conflicts to declare.
1
2 Dichloromethane
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Acknowledgements
13 Chloroform – substance information – ECHA, https://echa.
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The authors thank Nitto Belgium NV for funding the project.
This publication also includes results from the ReSolve
project. This project has received funding from the Bio-Based
Industries Joint Undertaking under the European Union‘s
Horizon2020 research and innovation programme under agree-
ment No 745450. The publication reflects only the authors’
view and the JU is not responsible for any use that may be
made of the information it contains. The authors would also
like to thank Dr James Sherwood and Dr Con Robert McElroy
for discussions throughout this work; the Biorenewable
Development Centre (BDC) for the use of their lab where Ames
testing was carried out and Emma Chotin for work carried out
during a summer internship.
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