Organic Letters
Letter
(6)Trost, B. M.;Koller, R.;Schaffner, B. Angew. Chem., Int. Ed. 2012,51,
8290.
̈
ASSOCIATED CONTENT
* Supporting Information
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S
(7) (a) Wu, Q.- F.; He, H.; Liu, W.-B.; You, S.-L. J. Am. Chem. Soc. 2010,
132, 11418. (b) Chen, W.; Hartwig, J. F. J. Am. Chem. Soc. 2013, 135,
2068. (c)Liu, W.-B.;Reeves, C. M.;Virgil, S. C.;Stoltz, B. M. J. Am. Chem.
Soc. 2013, 135, 10626. (d) Liu, W.-B.; Reeves, C. M.; Stoltz, B. M. J. Am.
Chem. Soc. 2013, 135, 17298. (e) Chen, W.; Hartwig, J. F. J. Am. Chem.
Soc. 2014, 136, 377. (f) Chen, W.; Chen, M.; Hartwig, J. F. J. Am. Chem.
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Chem., Int. Ed. 2016, 55, 5819. (h) Hethcox, J. C.; Shockley, S. E.; Stoltz,
B. M. Angew. Chem., Int. Ed. 2016, 55, 16092. (i) Jiang, X.; Hartwig, J. F.
Angew. Chem., Int. Ed. 2017, 56, 8887. (j) Sandmeier, T.; Krautwald, S.;
Carreira, E. M. Angew. Chem., Int. Ed. 2017, 56, 11515. For other
transition-metal-catalyzed AAA of prochiral enolates providing products
with vicinal chiral stereocenters, see: Pd: (k) Braun, M.; Laicher, F.;
Meier, T. Angew. Chem., Int. Ed. 2000, 39, 3494. (l) Zheng, W.-H.; Zheng,
B.-H.;Zhang, Y.;Hou,X.-L. J.Am. Chem. Soc. 2007,129,7718. (m)Chen,
J.-P.; Ding, C.-H.; Liu, W.; Hou, X.-L.; Dai, L.-X. J. Am. Chem. Soc. 2010,
132, 15493. (n)Li, X.-H.; Zheng, B.-H.;Ding, C.-H.; Hou, X.-L. Org. Lett.
2013, 15, 6086. (o) Liu, J.; Han, Z.; Wang, X.; Meng, F.; Wang, Z.; Ding,
K. Angew. Chem., Int. Ed. 2017, 56, 5050. Mo: (p) Trost, B. M.; Zhang, Y.
J. Am. Chem. Soc. 2007, 129, 14548. (q) Trost, B. M.; Zhang, Y. Chem. -
Eur. J. 2010, 16, 296. (r) Trost, B. M.; Miller, J. R.; Hoffman, C. M. J. Am.
Chem. Soc. 2011, 133, 8165.
TheSupportingInformationisavailablefreeofchargeontheACS
Experimental procedures and spectral data for all new
Crystallographic data for 6f (CIF)
Crystallographic data for 6l (CIF)
Crystallographic data for 11a (CIF)
Crystallographic data for 13 (CIF)
AUTHOR INFORMATION
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Corresponding Author
ORCID
Notes
The authors declare no competing financial interest.
(8) For stereodivergent synthesis, see: (a) Krautwald, S.; Sarlah, D.;
Schafroth, M. A.; Carreira, E. M. Science 2013, 340, 1065. (b) Oliveira, M.
T.; Luparia, M.; Audisio, D.; Maulide, N. Angew. Chem., Int. Ed. 2013, 52,
13149. (c) Krautwald, S.; Schafroth, M. A.; Sarlah, D.; Carreira, E. M. J.
Am. Chem. Soc. 2014, 136, 3020. (d) Schafroth, M. A.; Zuccarello, G.;
Krautwald, S.; Sarlah, D.; Carreira, E. M. Angew. Chem., Int. Ed. 2014, 53,
13898. (e) Næsborg, L.; Halskov, K. S.; Tur, F.; Mønsted, S. M. N.;
Jørgensen, K. A. Angew. Chem., Int. Ed. 2015, 54, 10193. (f) Sandmeier,
T.; Krautwald, S.; Zipfel, H. F.; Carreira, E. M. Angew. Chem., Int. Ed.
2015, 54, 14363. (g) Huo, X.; He, R.; Zhang, X.; Zhang, W. J. Am. Chem.
Soc. 2016, 138, 11093. (h) Jiang, X.; Beiger, J. J.; Hartwig, J. F. J. Am.
Chem. Soc. 2017, 139, 87. (i) Krautwald, S.; Carreira, E. M. J. Am. Chem.
Soc. 2017, 139, 5627.
ACKNOWLEDGMENTS
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We thank the NSFC (No. 21232004, 21472123, and
21620102003), STCSM (No. 15JC1402200), and SHMEC
(No. 201701070002E00030) for financial support.
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