Tetrahedron p. 3471 - 3480 (1987)
Update date:2022-08-26
Topics:
Bhatnagar, Subodh C.
Caruso, Andrew J.
Polonsky, Judith
Rodriguez, Berta Soto
Biologically inactive but easily available chaparrin 2a has been converted into potent antileukemic C-15 esters of glaucarubolone 2b and quassinoid analogs in which the C-15 ester side chain has been replaced by an alkyl or alkenyl group.The synthetic methodology developed has been applied to the preparation of C-15 ester derivatives 15, 16, 17 and quassinoid analogs 12, 13 and 14.
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Doi:10.1021/acs.inorgchem.6b00106
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