Synthesis p. 561 - 565 (1995)
Update date:2022-08-29
Topics:
Bouchra
Calinaud
Gelas
The ortho esterification of various glucofuranoses in the D-ribo, D-xylo and D-gluco series under kinetic control was obtained through the action of 1,1-dimethoxyethene (a ketene acetal) on the monosaccharide using mild acid conditions. The selective hydrolysis of the methoxyethylidene derivatives thus obtained, gave access to α-hydroxy acetates which are useful synthetic intermediates.
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(2004)Doi:10.1021/jo050695s
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(1984)