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Iodine pentoxide

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Name

Iodine pentoxide

EINECS 234-740-2
CAS No. 12029-98-0 Density 5.08 g/mL at 25 °C
PSA 77.51000 LogP 1.22780
Solubility Easily soluble in water; Soluble in methanol; Insoluble in absolute alcohol, ether, chloroform and carbon disulfide Melting Point 300-350 °C (dec.)
Formula I2O5 Boiling Point 184.3°C at 760 mmHg
Molecular Weight 333.806 Flash Point N/A
Transport Information UN 3085 5.1/PG 2 Appearance needle shaped crystals
Safety 17-26-27-36/37/39-45 Risk Codes 8-34
Molecular Structure Molecular Structure of 12029-98-0 (Iodine pentoxide) Hazard Symbols OxidizingO,CorrosiveC
Synonyms

Diiodinepentaoxide;Diiodine pentaoxide;Iodine pentoxide (I2O5);Iodine pentoxide;

Article Data 90

Iodine pentoxide Synthetic route

7553-56-2

iodine

10102-03-1

dinitrogen pentoxide

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) N2O5 (from P2O5 with HNO3); heating first to 50°C, at the end of reaction to 90°C;; drying on heating, removal of excessive iodine by sublimation; recrystallization in water several times, drying on heating to 220°C;;40%
In neat (no solvent) N2O5 (from P2O5 with HNO3); heating first to 50°C, at the end of reaction to 90°C;; drying on heating, removal of excessive iodine by sublimation; recrystallization in water several times, drying on heating to 220°C;;40%
In tetrachloromethane byproducts: O2; reaction of N2O5 with soln. of I2 in CCl4 at 0°C; at higher temp. formation of some O2;;
In tetrachloromethane byproducts: O2; reaction of N2O5 with soln. of I2 in CCl4 at 0°C; at higher temp. formation of some O2;;
7681-11-0

potassium iodide

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In water passing stream of O3 quickly through neutral soln.;;
In water passing stream of O3 quickly through neutral soln.;;0%
In neat (no solvent)
In neat (no solvent)
In water
12015-53-1

perchloric anhydride

7553-56-2

iodine

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In not given byproducts: HClO4; I2 reacts with chlorine heptoxide at normal temp. under explosion, at low temp. slowlier; reactn. product: white powder: heating (100°C) -> setting free HClO4, residue: I2O5;;
7553-56-2

iodine

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) reaction by influence of O3 on solid, dry I2;;
7681-11-0

potassium iodide

A

12029-98-0

iodine pentoxide

B

15056-35-6

periodate

C

15454-31-6

iodate

Conditions
ConditionsYield
With Na2CO3 or K2CO3 In not given reaction by use of a O3-O2 mixture in a Na2CO3- or K2CO3-containing alcaline 0.1n-KI soln. for a period of 20-30 min.;;
7681-11-0

potassium iodide

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In not given reaction by absorption of O3-containing O2 in a 3-8% KI soln.;;
10049-04-4, 25052-55-5

chlorine dioxide

7553-56-2

iodine

A

12029-98-0

iodine pentoxide

B

865-44-1

iodine trichloride

Conditions
ConditionsYield
In neat (no solvent) from ClO2 (from KClO3 and H2SO4) and dry iodine;; ICl3 evaporated on water bath by grinding; I2O5 very pure;;
In neat (no solvent) from ClO2 (from KClO3 and H2SO4) and dry iodine;; ICl3 evaporated on water bath by grinding; I2O5 very pure;;
10049-04-4, 25052-55-5

chlorine dioxide

7553-56-2

iodine

7782-50-5

chlorine

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) on heating I2 with euchlorine;;
In neat (no solvent) on heating I2 with euchlorine;;
In neat (no solvent)
7553-56-2

iodine

10102-03-1

dinitrogen pentoxide

A

12029-98-0

iodine pentoxide

B

iodine(III) nitrate

Conditions
ConditionsYield
In neat (no solvent) from solid N2O5 and dry I2;; product mixture;;
7553-56-2

iodine

12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) at red heat with platinum asbestos or -sponge;;0%
Electric Arc; mixture of I2O5 and other iodine oxides;;
In neat (no solvent) 90-100atm O2-pressure; heating to 250°C;;

Iodine pentoxide Specification

The Iodine pentoxide, with the CAS registry number 12029-98-0, is also known as Diiodine pentaoxide. It belongs to the product categories of Inorganics; Halogen oxide. Its EINECS number is 234-740-2. This chemical's molecular formula is I2O5 and molecular weight is 333.81. What's more, its systematic name is Oxybis(iodane) tetraoxide. This iodine oxide is the anhydride of iodic acid, and the only stable anhydride of iodine. This chemical is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from reductants, organic materials, metal powder and light.

Physical properties of Iodine pentoxide are: (1)ACD/LogP: -5.67; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.67; (4)ACD/LogD (pH 7.4): -5.67; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00 ; (7)#H bond acceptors: 5; (8)#H bond donors: 0; (9)#Freely Rotating Bonds: 2; (10)Polar Surface Area: 77.51 Å2.

Preparation: this chemical is produced by dehydrating iodic acid at 200 °C in a stream of dry air.

2HIO3 → I2O5 + H2O

When you are using this chemical, please be cautious about it as the following:
This chemical can cause burns. When contact with combustible material, it may cause fire. You should keep them away from combustible material. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. You must take off immediately all contaminated clothing. In case of accident or if you feel unwell, you should seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O=I(=O)OI(=O)=O
(2)Std. InChI: InChI=1S/I2O5/c3-1(4)7-2(5)6
(3)Std. InChIKey: BIZCJSDBWZTASZ-UHFFFAOYSA-N 

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