- L-Phenylglycine
- L-Phenylglycine methyl ester hydrochloride
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Cas Database |
| Name |
L-Phenylglycine methyl ester hydrochloride |
EINECS | N/A | ||||||||
| CAS No. | 15028-39-4 | Density | g/cm3 | ||||||||
| PSA | 52.32000 | LogP | 2.36170 | ||||||||
| Solubility | N/A | Melting Point |
200 °C (dec.)(lit.) |
||||||||
| Formula | C9H11 N O2 . Cl H | Boiling Point | 238.9°Cat760mmHg | ||||||||
| Molecular Weight | 201.653 | Flash Point | 104.7°C | ||||||||
| Transport Information | N/A | Appearance | N/A | ||||||||
| Safety |
|
Risk Codes | R36 | ||||||||
| Molecular Structure |
|
Hazard Symbols |
|
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| Synonyms |
Benzeneaceticacid, a-amino-, methyl ester,hydrochloride, (S)-; Benzeneacetic acid, a-amino-, methyl ester, hydrochloride, (aS)- (9CI); Glycine, 2-phenyl-,methyl ester, hydrochloride, L- (8CI);((S)-2-Methoxy-2-oxo-1-phenylethyl)ammonium chloride; (L)-Methylphenylglycinate hydrochloride; (S)-(+)-2-Phenylglycine methyl ester hydrochloride;(S)-2-Phenylglycine methyl ester hydrochloride; (S)-Methyl2-amino-2-phenylacetate hydrochloride; (S)-Phenylglycine methyl esterhydrochloride; L-Phenylglycine methyl ester hydrochloride; Methyl(2S)-2-amino-2-phenylacetate hydrochloride; Methyl (S)-amino(phenyl)acetatehydrochloride; Methyl (S)-phenylglycinate hydrochloride; MethylL-(+)-phenylglycinate hydrochloride; Methyl L-phenylglycinate hydrochloride;Phenylglycine methyl ester hydrochloride |
Article Data | 46 |
L-Phenylglycine methyl ester hydrochloride Synthetic route
- 235786-93-3
(S)-methyl 2-((S)-1-phenylethylamino)-2-phenylacetate
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride; hydrogen; palladium dihydroxide In methanol under 760.051 Torr; for 15h; | 100% |
| With hydrogenchloride; palladium hydroxide on carbon; hydrogen In methanol; water under 760.051 Torr; for 15h; optical yield given as %ee; | 100% |
| Conditions | Yield |
|---|---|
| With thionyl chloride for 10h; Ambient temperature; | 99% |
| With thionyl chloride for 8h; Heating; | 97% |
| With thionyl chloride In methanol at 20℃; Cooling with ice; | 97% |
- 2935-35-5
(S)-2-phenylglycine
- 77-76-9
2,2-dimethoxy-propane
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride In water at 20℃; | 99% |
| With hydrogenchloride at 20℃; for 18h; | 94% |
- 143978-88-5
N-tert-butoxycarbonyl-L-phenylglycine methyl ester
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride In dichloromethane; ethyl acetate at 20℃; for 0.833333h; Inert atmosphere; | 97% |
- 67-56-1
methanol
- 48108-77-6
(S)-α-phenylglycinenitrile
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With hydrogenchloride | 88% |
| With hydrogenchloride; water | 88% |
- 67-56-1
methanol
- 875-74-1
(R)-phenylglycine
A
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
B
- 19883-41-1
D-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With thionyl chloride for 20h; Ambient temperature; | A n/a B 76% |
- 6780-38-7
N-phthaloylglycine chloride
- 67627-99-0
N-benzyliden-α-phenyl-glycine methyl ester
C
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With 2,6-dimethylpyridine In toluene at 20℃; Staudinger Ketene Cycloaddition; Reflux; Inert atmosphere; | A 11% B 4% C 29% |
- 20698-91-3
(R)-methyl mandelate
A
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
B
- 19883-41-1
D-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| e.e. = 76percent; Multistep reaction. Title compound not separated from byproducts; |
- 67627-99-0
N-benzyliden-α-phenyl-glycine methyl ester
A
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
B
- 19883-41-1
D-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| Product distribution; multistep reaction; deracemisation was investigated by means of dipivaloyltartaric acids of different chirality in the presence of chiral amines of structure Ph-CHCH3-NHR; other temperature, acid, base; | |
| Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
- 153924-62-0
N-benzylidenephenylglycine methyl ester
A
- 15028-39-4
L-2-phenylglycine methyl ester hydrochloride
B
- 19883-41-1
D-phenylglycine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With (-)-O,O′-di-pivaloyl-L-tartaric acid; lithium (R)-N-methyl-N-α-methylbenzyl amide Product distribution; other lithium amides and diacyltartaric acides; | |
| With (R)-PhCH(CH3)NLiCH2CH3; (3R) HOOCCH(OCOtC4H9)CH(OCOtC4H9)COOH 1.) THF, - 50 deg C; 2.) THF, -70 deg C; Yield given. Multistep reaction. Yields of byproduct given; |
L-Phenylglycine methyl ester hydrochloride Chemical Properties
Molecular Structure of L-Phenylglycine methyl ester hydrochloride (15028-39-4):
Systematic Name: Methyl (2S)-2-amino-2-phenyl-acetate hydrochloride
Molecular Formula: C9H12ClNO2
Molecular Weight: 201.6501
SMILES: Cl.O=C(OC)[C@@H](N)c1ccccc1
InChI: InChI=1/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m0./s1
InChIKey: DTHMTBUWTGVEFG-QRPNPIFTBM
Flash Point: 104.7 °C
Melting Point: 200 °C (dec.)(lit.)
Boiling Point: 238.9 °C at 760 mmHg
Enthalpy of Vaporization: 47.58 kJ/mol
Vapour Pressure: 0.0412 mmHg at 25 °C
Storage Temp.: 2-8 °C
L-Phenylglycine methyl ester hydrochloride Safety Profile
Safety Information of L-Phenylglycine methyl ester hydrochloride (15028-39-4):
Hazard Codes: Xi .gif){kind=small}
Risk Statements: 36
36: Irritating to the eyes
Safety Statements: 26-36/37
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37: Wear suitable protective clothing and gloves
WGK Germany: 3
L-Phenylglycine methyl ester hydrochloride Specification
L-Phenylglycine methyl ester hydrochloride (15028-39-4) is also known as H-PHG-OME HCL ; L-Phenyl glycine methyl ester HCL ; L-Phenylglycine methyl ester hydrochloride salt ; H-(PH)GLY-OME HCL; (S)-(+)-2-Phenylglycine methyl ester hydrochlorid ; Phenylglycine-OME HCL .
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