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Cas Database |
| Name |
Leaf alcohol |
EINECS | 213-192-8 |
| CAS No. | 928-96-1 | Density | 0.843 g/cm3 |
| PSA | 20.23000 | LogP | 1.33500 |
| Solubility | insoluble in water | Melting Point |
-60oC |
| Formula | C6H12O | Boiling Point | 156.5 °C at 760 mmHg |
| Molecular Weight | 100.161 | Flash Point | 44.4 °C |
| Transport Information | UN 1987 3/PG 3 | Appearance | colourless liquid |
| Safety | 16 | Risk Codes | 10 |
| Molecular Structure |
|
Hazard Symbols |
 F
|
| Synonyms |
3-Hexen-1-ol,(Z)- (8CI);3-Hexen-1-ol, cis- (5CI);(3Z)-3-Hexen-1-ol;(3Z)-Hexenol;(Z)-3-Hexen-1-ol;(Z)-3-Hexenol;(Z)-Hex-3-en-1-ol;3Z-Hexen-1-ol;Blaetteralkohol;ENT 25091;Folic alcohol;Green leaf alcohol;cis-3-Hexen-1-ol;cis-3-Hexene-1-ol;cis-3-Hexenol; |
Article Data | 85 |
Leaf alcohol Synthetic route
| Conditions | Yield |
|---|---|
| With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.283333h; | 100% |
| With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760.051 Torr; | 99% |
| With trichlorosilane; silica gel; acetic acid; tetrakis(triphenylphosphine) palladium(0) In dichloromethane for 3h; Ambient temperature; | 96% |
| Conditions | Yield |
|---|---|
| With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics; | A 99% B n/a |
| With hydrogen In methanol at 30℃; under 760.051 Torr; for 3h; | A 99% B 1% |
| With hydrogen In methanol at 20℃; under 150.015 - 900.09 Torr; for 0.0116667h; Inert atmosphere; Schlenk technique; Green chemistry; | A n/a B n/a |
- 111-28-4
2,4-hexadiene-1-ol
A
- 928-96-1
(Z)-3-Hexen-1-ol
B
- 928-97-2
(E)-3-hexen-1-ol
C
- 6126-50-7, 928-91-6, 928-92-7
hex-4-en-1-ol
D
- 111-27-3
hexan-1-ol
| Conditions | Yield |
|---|---|
| With hydrogen; (methyl benzoate)Cr(CO)6 In methanol at 190 - 200℃; under 36775.4 Torr; for 2h; | A 92.5% B 4.6% C 2.3% D 0.6% |
| With hydrogen; (1,2,4,5-tetramethylbenzene)tricarbonylchromium(0) In methanol at 190 - 200℃; under 36775.4 Torr; for 4h; Product distribution; other arene ligands, other solvents; also in absence of arene ligands; |
| Conditions | Yield |
|---|---|
| With hydrogen In methanol at 20℃; under 1800.18 Torr; Catalytic behavior; Reagent/catalyst; | A 88% B n/a C n/a |
| With hydrogen; poly(N-vinyl-2-pyrrolidone)-stabilised Pd-nanoclusters In methanol at 29℃; | |
| With hydrogen In isopropyl alcohol at 30℃; under 2250.23 Torr; for 20h; Autoclave; optical yield given as %de; stereoselective reaction; |
- 17102-64-6
Sorbyl alcohol
- 928-96-1
(Z)-3-Hexen-1-ol
| Conditions | Yield |
|---|---|
| With Na12(Ga4(1,5-bis(2,3-dihydroxybenzamido)naphthalene))6; [(DMPE)Rh(COD)][BF4]; hydrogen In water-d2 at 20℃; for 12h; | 84% |
| With hydrogen; chromium(0) hexacarbonyl In hexane at 160 - 180℃; under 38000 - 60800 Torr; for 4h; | |
| With hydrogen; [(η5-C5Me5)Ru(η4-MeCH=CHCH=CHCO2H)] triflate In ethylene glycol at 40℃; under 15001.5 Torr; for 0.42h; Catalytic hydrogenation; |
| Conditions | Yield |
|---|---|
| With 1% Rh/Al2O3; hydrogen; iron In ethanol at 120℃; under 15001.5 Torr; for 4h; Reagent/catalyst; Temperature; Pressure; Solvent; Autoclave; | 80.35% |
| With aldehyde reductase; nicotinamide adenine dinucleotide phosphate Enzymatic reaction; |
- 55230-25-6
6-methyl-3,6-dihydro-2H-pyran
- 928-96-1
(Z)-3-Hexen-1-ol
| Conditions | Yield |
|---|---|
| With calcium; ethylenediamine at 90℃; for 8h; | 60% |
- 627-27-0
homoalylic alcohol
- 96-10-6
diethylaluminium chloride
A
- 589-35-5, 20281-83-8
3-methyl-1-pentanol
B
- 928-96-1
(Z)-3-Hexen-1-ol
C
- 928-97-2
(E)-3-hexen-1-ol
D
- 71-36-3
butan-1-ol
E
- 111-27-3
hexan-1-ol
| Conditions | Yield |
|---|---|
| With titanium tetrachloride In dichloromethane at -45℃; for 2h; Mechanism; Product distribution; variation of added base; | A 13% B 3% C 18% D 20% E 21% |
| Conditions | Yield |
|---|---|
| With Pd-BaSO4; benzene at 50℃; Hydrogenation; | |
| With lithium; Trimethylenediamine at 25℃; for 2h; | |
| With palladium/highly-ordered mesoporous silica supported 3-D pore network(3.7) 1-phenylethan-1-amine 0.02 for 2.91667h; | |
| With hydrogen In methanol at 20℃; under 862.586 Torr; for 8h; Catalytic behavior; Flow reactor; | A n/a B n/a |
- 98486-14-7
cis/trans-3-chloro-2-ethyltetrahydrofuran
A
- 928-96-1
(Z)-3-Hexen-1-ol
B
- 928-97-2
(E)-3-hexen-1-ol
| Conditions | Yield |
|---|---|
| With samarium diiodide In tetrahydrofuran Product distribution; Heating; using dipolar-aprotic cosolvents; | |
| With samarium diiodide In tetrahydrofuran for 5h; Heating; Yield given. Yields of byproduct given; |
Leaf alcohol Chemical Properties
Molecular Formula:C6H12O
Molecular Weight:100.18
EINECS:213-192-8
Density:0.848g/mL at 25 °C(lit.)
Boiling Point:156-157 °C
Flash Point:44 °C
Water Solubility:Insoluble
Appearance:Colourless liquid
cis-3-HEXENOL's(928-96-1) Synonyms: (3Z)-3-Hexen-1-ol;(z)-3-hexen-1-o;(Z)-3-Hexen-1-ol;(Z)-Hex-3-en-1-ol;(Z)-Hex-3-ene-1-ol;(Z)Hex-3-enol;1-Hydroxyhex-3-ene;3-(Z)-Hexenol
cis-3-HEXENOL's(928-96-1) Molecular Structure:
Leaf alcohol Toxicity Data With Reference
| 1. | orl-rat LD50:4700 mg/kg | FCTXAV Food and Cosmetics Toxicology. 12 (1974),909. | ||
| 2. | ipr-rat LD50:600 mg/kg | FCTXAV Food and Cosmetics Toxicology. 7 (1969),451. | ||
| 3. | orl-mus LD50:7000 mg/kg | FCTXAV Food and Cosmetics Toxicology. 7 (1969),451. | ||
| 4. | ipr-mus LD50:400 mg/kg | FCTXAV Food and Cosmetics Toxicology. 7 (1969),451. |
Leaf alcohol Consensus Reports
Leaf alcohol Safety Profile
A poison by intraperitoneal route. Mildly toxic by ingestion. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..
Safety Information of cis-3-HEXENOL(928-96-1)
Hazard Codes 
F
Risk Statements 10
Safety Statements 16
RIDADR UN 1987 3/PG 3
WGK Germany 1
RTECS MP8400000
F 10
HazardClass 3
PackingGroup III
HS Code 29052990
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