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Mercuric trifluoroacetate

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Name

Mercuric trifluoroacetate

EINECS 236-250-4
CAS No. 13257-51-7 Density N/A
PSA 52.60000 LogP 1.10990
Solubility soluble in water Melting Point 171-173 °C(lit.)
Formula C4F6HgO4 Boiling Point 72.2 °C at 760 mmHg
Molecular Weight 426.622 Flash Point N/A
Transport Information UN 2025 Appearance almost white to light beige crystalline powder
Safety 13-28-36-45-60-61-28A Risk Codes 26/27/28-33-50/53
Molecular Structure Molecular Structure of 13257-51-7 (Mercuric trifluoroacetate) Hazard Symbols VeryT+, DangerousN, ToxicT
Synonyms

Aceticacid, trifluoro-, mercury(2+) salt (8CI,9CI);Bis(trifluoroacetato)mercury;Bis(trifluoroacetoxy)mercury;Mercuric trifluoroacetate;Mercurybis(trifluoroacetate);Mercury(2+) trifluoroacetate;Mercury(II)bis(trifluoroacetate);Mercury(II) trifluoroacetate;Trifluoroacetic acidmercury(2+) salt;

Article Data 9

Mercuric trifluoroacetate Synthetic route

76-05-1

trifluoroacetic acid

mercury(II) oxide

13257-51-7

mercury(II) trifluoroacetate

Conditions
ConditionsYield
at 80℃; for 0.5h;100%
In neat (no solvent) HgO and CF3COOH were heated under reflux, CF3COOH was distilled off at 150°C;
431-45-8

trifluoroacetyl hypobromite

C2F3O2(1-)*Br(1-)*Hg(2+)

13257-51-7

mercury(II) trifluoroacetate

Conditions
ConditionsYield
In trifluoroacetic acid at 25℃; Equilibrium constant;
359-47-7

Trifluoracetylhypoiodit

C2F3O2(1-)*Hg(2+)*I(1-)

13257-51-7

mercury(II) trifluoroacetate

Conditions
ConditionsYield
In trifluoroacetic acid at 25℃; Equilibrium constant;

mercury(I) trifluoroacetate

A

13257-51-7

mercury(II) trifluoroacetate

B

mercury(I) chloride

Conditions
ConditionsYield
With HCl In trifluoroacetic acid
With HCl In trifluoroacetic acid
13257-51-7

mercury(II) trifluoroacetate

2-methyl-4,4,5,5-tetramethyl-1,3-dioxolanium perchlorate

A

76-09-5

2,3-dimethyl-2,3-butane diol

B

C4H2ClF3Hg2O8

Conditions
ConditionsYield
In ethanol for 0.25h; Heating; Yields of byproduct given;A n/a
B 99%
17282-45-0

1-[2-(4-bromo-phenyl)-2-oxo-ethyl]-pyridinium betaine

13257-51-7

mercury(II) trifluoroacetate

255737-12-3

1-(2-oxo-2-(4-bromophenyl)-1-trifluoroacetoxymercurioethyl)pyridinium trifluoroacetate

Conditions
ConditionsYield
In water Hg-compd. addn. to soln. of ylide, after 5 min solvent removing (reducedpressure); residue washing (hexane), drying; elem. anal.;99%
255737-19-0

CH2C5H4NCH2C(O)C6H5

13257-51-7

mercury(II) trifluoroacetate

255737-29-2

2-methyl-1-[2-(4-nitrophenyl)-2-oxo-1-trifluoroacetoxymercurioethyl]-2-methylpyridinium trifluoroacetate

Conditions
ConditionsYield
In ethanol Hg-compd. addn. to soln. of ylide; after 10 min solvent removing (reduced pressure), residue washing (diethyl ether, hexane), drying; elem. anal.;99%
25357-54-4

N-4-Nitrophenacyl-pyridinium-ylid

13257-51-7

mercury(II) trifluoroacetate

255737-14-5

1-(2-oxo-2-(4-nitrophenyl)-1-trifluoroacetoxymercurioethyl)pyridinium trifluoroacetate

Conditions
ConditionsYield
In water Hg-compd. addn. to soln. of ylide, after 0.2 h min solvent removing (reduced pressure); residue washing (hexane), drying; elem. anal.;99%
255737-20-3

CH2C5H4NCH2C(O)C6H4Br

13257-51-7

mercury(II) trifluoroacetate

255737-31-6

4-methyl-1-[2-(4-nitrophenyl)-2-oxo-1-trifluoroacetoxymercurioethyl]-2-methylpyridinium trifluoroacetate

Conditions
ConditionsYield
In ethanol Hg-compd. addn. to soln. of ylide; after 0.2 h solvent removing (reduced pressure), residue washing, hexane), drying; elem. anal.;99%
25407-30-1

4-nitrophenacylpyridinium bromide

13257-51-7

mercury(II) trifluoroacetate

255737-10-1

1-(2-oxo-2-(4-nitrophenyl)-1-trifluoroacetoxymercurioethyl)pyridinium bromide

Conditions
ConditionsYield
In ethanol byproducts: CF3COOH; refluxing (1 h); solvent removing (reduced pressure, room temperature), residue washing (diethyl ether, hexane), drying; elem. anal.;99%

Mercuric trifluoroacetate Specification

The IUPAC name of Mercuric trifluoroacetate is mercury(2+); 2,2,2-trifluoroacetate . With the CAS registry number 13257-51-7, it is also named as Bis(trifluoroacetato)mercury ; Acetic acid, 2,2,2-trifluoro-, mercury salt (2:1) ; Mercury bis(trifluoroacetate) ; Mercury(II) trifluoroacetate . It is hygroscopic and can absorb moisture from the air. Mercuric trifluoroacetate is raw material of fine chemicals and pharmaceutical intermediates. So it can be used in the pharmaceutical synthesis. Both linear and cross-linked copolymers of N-vinylcarbazole and methylacrylate can be prepared and mercuriated by using mercury trifluoroacetate in THF or dichloromethane. The role of mercuric trifluoroacetate as reactive agent and activator in reactions of various Se-alkyl phosphoroselenoates with O- and N-nucleophiles is examined.

 Mercuric trifluoroacetate is very toxic by inhalation, in contact with skin and if swallowed. It has danger of cumulative effects. It is also very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. So we must keep Mercuric trifluoroacetate away from food, drink and animal foodstuffs. After contact with skin, wash immediately with plenty of soap-suds. If you want contact with it, you must wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 

The products indicated contain mercury. Don't put products containing mercury in the trash. So this material and its container must be disposed of as hazardous waste. Products containing mercury may be regulated by Local, State, or Federal Laws. Some products containing mercury are not available for sale in some states.

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