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Methyl 2-fluoroacrylate
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Name

Methyl 2-fluoroacrylate

 EINECS N/A
CAS No. 2343-89-7 Density 1.057 g/cm3
PSA 26.30000 LogP 0.64260
Solubility Slightly soluble in water. Melting Point N/A
Formula C4H5FO2 Boiling Point 75.9 °C at 760 mmHg
Molecular Weight 104.081 Flash Point 1.1 °C
Transport Information UN 1993 Appearance N/A
Safety 16-26-36 Risk Codes 10-36/37/38
Molecular Structure Molecular Structure of 2343-89-7 (METHYL 2-FLUOROACRYLATE) Hazard Symbols IrritantXi
Synonyms

Acrylicacid, 2-fluoro-, methyl ester (6CI,7CI,8CI);Methyl a-fluoroacrylate;a-Fluoroacrylic acid methyl ester;

Article Data 34

Methyl 2-fluoroacrylate Synthetic route

85345-88-6

Methyl 2-Fluoro-3-(4-toluenesulfonyloxy)propanoate

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With potassium phtalimide at -78 - 150℃; under 0.01 Torr;97%
55900-27-1

Methyl 3-chloro-2-fluoropropanoate

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium phosphate In 1-methyl-pyrrolidin-2-one at 150℃; under 112.511 - 225.023 Torr;95%
With dimethyl amine In diethyl ether; benzene
67-56-1

methanol

430-99-9

2-fluoroacrylic acid

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With thionyl chloride at 5 - 35℃; for 2h; Concentration; Reagent/catalyst;93%

dimethyl 2-fluoro-2-chloromethylmalonate

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium carbonate In 1-methyl-pyrrolidin-2-one at 150℃; under 225.023 Torr; for 4h;92%
67-56-1

methanol

2317-91-1

1-chloro-1-fluoroethane

201230-82-2

carbon monoxide

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II); triethylamine at 100℃; under 5250.53 Torr; for 8h; Reagent/catalyst; Autoclave;91.8%
With bis(tri-t-butylphosphine)palladium(0) at 100℃; for 18h; Reagent/catalyst; Time; Autoclave;77.4%
67-56-1

methanol

420-25-7

1-bromo-1-fluoroethylene

201230-82-2

carbon monoxide

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; lithium carbonate; triethylamine at 90℃; for 6h; Reagent/catalyst; Temperature; Autoclave;90.7%
With dichloro[4,5-bis(diphenylphosphino)-9,9’-dimethylxanthene]palladium(II); triethylamine at 100℃; under 7500.75 Torr; for 8h; Reagent/catalyst; Autoclave;90.1%
With bis-triphenylphosphine-palladium(II) chloride; tributyl-amine; lithium carbonate at 90℃; under 7500.75 Torr; for 6h; Reagent/catalyst; Autoclave;71.8 g

1-chloro-1-fluoro-2,2-dimethoxycyclopropane

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; methoxybenzene at 120 - 130℃; under 500 Torr; Reagent/catalyst; Temperature;89.5%
With 2,6-di-tert-butyl-4-methyl-phenol at 145℃; under 360 Torr;12.3 g
2365-93-7

methyl 3-bromo-2-fluoro-2-chloropropanoate

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine; sulfuric acid; zinc In water at 82 - 86℃; for 0.333333h;85%
With hydrogen sulfide; sodium N-nitroso-N-phenylhydroxylaminate; zinc In water at 100℃;82%
With zinc80%
With sulfuric acid; zinc

C13H13FO6

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine In sulfolane at 180℃; for 6h;83.9%

C14H15FO6

2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 4-methoxy-phenol at 170℃; for 9h;81.2%

Methyl 2-fluoroacrylate Specification

The cas register number of Methyl 2-fluoroacrylate is 2343-89-7. In addition, the molecular formula is C4H5FO2 and the molecular weight is 104.08. The systematic name about this chemical is methyl 2-fluoroprop-2-enoate. Besides, it is a irritating chemical and should be stored in a cool and dry place.

Physical properties about Methyl 2-fluoroacrylate are: (1)ACD/LogP: 0.68; (2)ACD/LogD (pH 5.5): 0.68; (3)ACD/LogD (pH 7.4): 0.68; (4)ACD/BCF (pH 5.5): 1.95; (5)ACD/BCF (pH 7.4): 1.95; (6)ACD/KOC (pH 5.5): 56.12; (7)ACD/KOC (pH 7.4): 56.12; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 2; (10)Polar Surface Area: 26.3 Å2; (11)Index of Refraction: 1.366; (12)Molar Refractivity: 22.08 cm3; (13)Molar Volume: 98.3 cm3; (14)Polarizability: 8.75 ×10-24cm3; (15)Surface Tension: 21 dyne/cm; (16)Density: 1.057 g/cm3; (17)Flash Point: 1.1 °C; (18)Enthalpy of Vaporization: 31.7 kJ/mol; (19)Boiling Point: 75.9 °C at 760 mmHg; (20)Vapour Pressure: 103 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable and it is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. And you should keep away from sources of ignition. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: F/C(=C)C(=O)OC 
(2)Std. InChI: InChI=1S/C4H5FO2/c1-3(5)4(6)7-2/h1H2,2H3
(3)Std. InChIKey: ZTZJVAOTIOAZGZ-UHFFFAOYSA-N

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