- Phenarsazine chloride
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| Name |
Phenarsazine chloride |
EINECS | N/A |
| CAS No. | 578-94-9 | Density | g/cm3 |
| PSA | 12.03000 | LogP | 2.22610 |
| Solubility | N/A | Melting Point |
195° |
| Formula | C12H9 As Cl N | Boiling Point | 401.6°Cat760mmHg |
| Molecular Weight | 277.585 | Flash Point | 196.7°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Human poison by inhalation. Poison experimentally by intravenous route. Human systemic effects by inhalation: changes in function or structure of salivary glands, nausea or vomiting, cough. May be irritating to skin, eyes, and mucous membranes. A vomiting type of poison gas (non-persistent). When heated to decomposition it emits very toxic fumes of As and Cl−. See also ARSENIC COMPOUNDS. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | Toxic by inhalation and ingestion, strong irritant. |
| Synonyms |
Phenarsazine,1-chloro-1,6-dihydro- (3CI); 10-Chloro-5,10-dihydroarsacridine;10-Chloro-5,10-dihydrophenarsazine; 5-Aza-10-arsenaanthracene chloride;5-Chloro-5,10-dihydrophenarsazine; Adamsit; Adamsite; Adamsyte; DM; DM (arseniccompound); Diphenylaminechlorarsine; Diphenylaminechloroarsine; NSC 86138;Phenarsazine chloride |
Phenarsazine chloride Chemical Properties
IUPAC Name: 10-Chloro-5H-phenarsazinine
Synonyms of Phenarsazine chloride (CAS NO.578-94-9) :10-Chloro-5,10-dihydrophenarsazinine ; Phenarsazine chloride ; Phenarsazine, 10-chloro-5,10-dihydro-; 5-Aza-10-arsenaanthracene chloride
CAS NO: 578-94-9
Molecular Formula:C12H9AsClN
Molecular Weight :277.5812
Molecular Structure :
EINECS: 209-433-1
Flash Point: 196.7 °C
Enthalpy of Vaporization: 65.26 kJ/mol
Boiling Point: 401.6 °C at 760 mmHg
Vapour Pressure: 1.17E-06 mmHg at 25°C
Phenarsazine chloride Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| human | LCLo | inhalation | 54ppm/30M (54ppm) | National Technical Information Service. Vol. PB214-270, | |
| mouse | LD50 | intravenous | 35mg/kg (35mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11444, | |
| rabbit | LD50 | intravenous | 6mg/kg (6mg/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 194, 1962. |
Phenarsazine chloride Consensus Reports
Arsenic and its compounds are on the Community Right-To-Know List.
Phenarsazine chloride Safety Profile
Human poison by inhalation. Poison experimentally by intravenous route. Human systemic effects by inhalation: changes in function or structure of salivary glands, nausea or vomiting, cough. May be irritating to skin, eyes, and mucous membranes. A vomiting type of poison gas (non-persistent). When heated to decomposition it emits very toxic fumes of As and Cl−. See also ARSENIC COMPOUNDS.
RIDADR 1698
HazardClass 6.1(a)
PackingGroup I
Phenarsazine chloride Standards and Recommendations
DOT Classification: 6.1; Label: Poison
OSHA PEL: TWA 0.5 mg(As)/m3
Phenarsazine chloride Specification
1.General Description : Phenarsazine chloride (CAS NO.578-94-9) is in the form of yellow crystals. The vapors are very irritating to the eyes and mucous membranes and are also nauseating.
2.Reactivity Profile: Organometallics, such as 10-chloro-5,10-dihydrophenarsazine , are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
3.Health Hazard: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
4.Fire Hazard: Non-combustible, Phenarsazine chloride (CAS NO.578-94-9) does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
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