1,3,3,3-Tetrafluoroprop-1-ene

Base Information

• Chemical Name: 1,3,3,3-Tetrafluoroprop-1-ene
• CAS No.: 29118-24-9
• Deprecated CAS: 2072839-56-4,1638974-96-5,2248137-12-2
• Molecular Formula: C3H2F4
• Molecular Weight: 114.042
• Hs Code.: 2903510020
• European Community (EC) Number: 471-480-0,688-097-1,810-135-4
• UNII: 5I2481UOO8
• DSSTox Substance ID: DTXSID10885446
• Nikkaji Number: J1.348.007I,J2.164.369F
• Wikidata: Q2806557
• Mol file: 29118-24-9.mol

Synonyms:1,3,3,3-tetrafluoropropene;HFO-1234ze;trans-1,3,3,3-tetrafluoropropene

Chemical Property of 1,3,3,3-Tetrafluoroprop-1-ene

Chemical Property:

• Vapor Pressure: 3440mmHg at 25°C
• Boiling Point: -16 °C
• PSA: 0.00000
• Density: 1.219±0.06 g/cm3(Predicted)
• LogP: 2.03190
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 114.00926271
• Heavy Atom Count: 7
• Complexity: 69.5

Purity/Quality:

99.9% ^*data from raw suppliers

(E)-1,3,3,3-Tetrafluoropropene 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,F:Flammable/Irritant
• Statements: R11:
• Safety Statements: S9-16-33:

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=CF)C(F)(F)F
• Isomeric SMILES: C(=C/F)\C(F)(F)F

Technology Process of 1,3,3,3-Tetrafluoroprop-1-ene

There total 66 articles about 1,3,3,3-Tetrafluoroprop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.4%

1,3,3,3-tetrafluoro-propene (1645-83-6) → 1,1,1,3,3-Pentafluoropropane (460-73-1) + trans-1,3,3,3-tetrafluoropropene (29118-24-9)

Guidance literature:

With hydrogen fluoride; chlorine; at 180 ℃; for 6h;

Reference yield: 46.6%

trans-1-chloro-3,3,3-trifluoropropene (102687-65-0) → 1,1,1,3,3-Pentafluoropropane (460-73-1) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With aluminum oxide; chromium(III) chloride hexahydrate; hydrogen fluoride; at 360 - 450 ℃; for 1h; under 750.075 - 1500.15 Torr; Inert atmosphere;

Reference yield: 29.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → 1,2,3,3,3-pentafluoroprop-1-ene (2252-83-7,5528-43-8,5595-10-8) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With dimethylsulfide borane complex; In benzene-d6; at 100 ℃; for 96h; Time;

upstream raw materials:

1,1,1,3-tetrafluoro-3-iodo-propane

1,1,1,2,3-pentafluoropropane

(Z)-1,3,3,3-tetrafluoropropene

trans-1-chloro-3,3,3-trifluoropropene

Downstream raw materials:

1,1,1,3,3,3-hexafluoropropane

2,3,3,3-tetrafluoro-propene

1,1,1,3,3-Pentafluoropropane

(Z)-1,3,3,3-tetrafluoropropene

Refernces

• 1、 Braun, Thomas,Talavera, Maria. "Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt3)3] (E=H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps". . p. 11926 - 11934. Retrieved 2021.
• 2、 Gregory,R. et al.. "-". . p. 1750 - 1758. Retrieved 1970.
• 3、 -. "Preparation method of Z-1-halogen-3, 3, 3-trifluoropropene". Paragraph 0042-0044. . Retrieved 2021/05/01.
• 4、 -. "Preparation method of E-1, 3, 3, 3-tetrafluoropropene". Paragraph 0036-0058. . Retrieved 2021/05/19.