Cadmium, bis[tris(pentafluorophenyl)germyl]-

Base Information

• Chemical Name: Cadmium, bis[tris(pentafluorophenyl)germyl]-
• CAS No.: 35098-95-4
• Molecular Formula: C36CdF30Ge2
• Molecular Weight: 1259.94
• Mol file: 35098-95-4.mol

Synonyms:

Chemical Property of Cadmium, bis[tris(pentafluorophenyl)germyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cadmium, bis[tris(pentafluorophenyl)germyl]-

There total 1 articles about Cadmium, bis[tris(pentafluorophenyl)germyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

diethylcadmium (592-02-9) + tris(pentafuorophenyl)germane (42371-50-6) → bis-{tris-(pentafluoro phenyl) germanium} cadmium (35098-95-4)

Guidance literature:

In toluene; heating from 20 to 100°C within 3 hours and heating at 100°C for 30 minutes;;

DOI:10.1016/S0022-328X(00)84040-1

Reference yield: 79.0%

vanadocene + bis-{tris-(pentafluoro phenyl) germanium} cadmium (35098-95-4) → (C5H5)2VGe(C6F5)3 + cadmium (7440-43-9)

Guidance literature:

In toluene; to Cd compd. soln. added complex soln., reacted for 20 h at 20°C; Cd centrifugated, org. layer decanted, concd. (vac.), pptd. (hexane, for 24 h at -78°C);

DOI:10.1016/0022-328X(84)85006-8

Reference yield: 72.1%

bis-{tris-(pentafluoro phenyl) germanium} cadmium (35098-95-4) + Pr(3+)*3OC(CH3)3(1-)=Pr(OC(CH3)3)3 + tris(pentafuorophenyl)germane (42371-50-6) → Pr(3+)*7(C6F5)3Ge(1-)*2Cd(2+)*3CH3OCH2CH2OCH3=([(C6F5)3Ge]7Cd2)Pr*3CH3OCH2CH2OCH3

Guidance literature:

In 1,2-dimethoxyethane; byproducts: t-BuOH; Ge- and Ge/Cd-compd. solns. addn. to Pr-compd. soln., mixt. heating (sealed evac. ampule, 50°C, 1 h); solvent and volatiles removal (vac.-condensation), residue washing several times (toluene), vac.-drying; elem. anal., GLC anal.;

upstream raw materials:

diethylcadmium

tris(pentafuorophenyl)germane

Downstream raw materials:

Cd{Ge(C₆F₅)3}2{Sb(C₂H₅)3}2

(C₆F₅)3GeCdPt{P(C₆H₅)3}2Ge(C₆F₅)3

tris(pentafluorophenyl)germanium bromide

bis[tris(pentafluorophenyl)germyl]mercury